Browse
Submit Data
Databases
API
Help

Dataset Information

15 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Chlorido[6-phenyl-4-(p-tol-yl)-2,2'-bipyridyl-κN,N']platinum(II).

ABSTRACT: The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent mol-ecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short inter-molecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC(3) and PtN(2)C(2) rings, respectively, indicate the existence of π-π inter-actions, which link the mol-ecules into stacks along the a axis. The crystal structure is further stabilized by weak C-H⋯π inter-actions.

SUBMITTER: Lu HB

PROVIDER: S-EPMC2961937 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

(2,2'-Bipyridyl-κN,N')chlorido(dl-threoninato-κN,O)copper(II) monohydrate.

Project description:In the title compound, [Cu(C(4)H(8)NO(3))Cl(C(10)H(8)N(2))]·H(2)O, the Cu(II) atom is in a slightly distorted square-pyramidal coordination geometry with the basal plane defined by the two N atoms of the bipyridine ligand and the N and O atoms from the threoninate ion and the apical site occupied by the Cl atom. In the crystal, inter-molecular O-H⋯O, N-H⋯O, O-H⋯Cl, C-H⋯O and C-H⋯Cl inter-actions link the mol-ecules into a three-dimensional network. A π-π inter-action with a centroid-centroid distance of 3.461 (1) Å is also present.

| S-EPMC3051714 | biostudies-literature

Chlorido{5-chloro-2-[2-(methyl-sulfanyl)phenyl-diazen-yl]phenyl}-platinum(II).

Project description:The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra-coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol-ecules dimerize through a nonbonded S⋯S inter-action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter-molecular π-π inter-actions; the centroid-centroid distances are 3.804 (3), 3.638 (3), 3.804 (3) and 3.638 (3) Å, and the corresponding perpendicular distances are 3.369, 3.448, 3.406 and 3.466 Å.

| S-EPMC2960293 | biostudies-literature

Chlorido(dimethyl sulfoxide-?S)[2-(2-pyrid-yl)phenyl-?N,C]platinum(II).

Project description:In the title compound, [Pt(C(11)H(8)N)Cl(C(2)H(6)OS)], the S atom of dimethyl sulfoxide is trans to the pyridyl N atom [Pt-S = 2.2181?(11)?Å] and the chlorido ligand is trans to the carbon donor of 2-(2-pyrid-yl)phenyl [Pt-Cl = 2.4202?(10)?Å]. The [2-(2-pyrid-yl)phen-yl]platinum(II) unit forms a one-dimensional stack along the c axis with two independent inter-planar separations of 3.44?(9) and 3.50?(2)?Å.

| S-EPMC2959355 | biostudies-literature

(2,2'-Bipyridine-κN,N')chlorido[4'-(2,5-dimethoxy-phen-yl)-2,2':6',2''-terpyridine-κN,N',N'']ruthenium(II) hexa-fluorido-phosphate acetonitrile monosolvate.

Project description:In the title compound, [RuCl(C(10)H(8)N(2))(C(23)H(19)N(3)O(2))]PF(6)·CH(3)CN, the ligand environment about the Ru(II) atom is distorted octa-hedral, with the substituted terpyridyl ligand coordinated in a meridional fashion, the bipyridyl ligand coordinated in a cis fashion and the Cl atom trans to one of the bipyridyl N atoms. The Ru-N distances are in the range 2.036 (2)-2.084 (2) Å with the exception of the central Ru-N bond from the terpyridyl ligand, which is shorter [1.9503 (19) Å], as expected. The pendant dimethoxy-phenyl substituent is not coplanar with the terpyridyl unit; the dihedral angle between the central pyridyl ring and the benzene ring is 46.72 (11)°. The anion is disordered equally over two positions around an F-P-F bond axis.

| S-EPMC2969997 | biostudies-literature

Bis(2,2'-bipyridyl-κN,N')(sulfato-κO,O')zinc(II) ethane-1,2-diol solvate.

Project description:The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octa-hedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2'-bipyridine ligands. The Zn-N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn-O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are connected by inter-molecular O-H⋯O hydrogen bonding, which leads to additional stabilization of the structure.

| S-EPMC2979970 | biostudies-literature

Chlorido(1,2-dimethyl-1H-imidazole-κN){2-[(diphen-oxy-phosphan-yl)-oxy]phenyl-κC,P}palladium(II).

Project description:The Pd atom in the title compound, [Pd(C(18)H(14)O(3)P)Cl(C(5)H(8)N(2))], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C-H⋯O and C-H⋯Cl hydrogen-bond inter-actions. One of the phenyl rings is disordered over two almost equally occupied sites.

| S-EPMC3274940 | biostudies-literature

Crystal structure of di-μ-chlorido-bis(chlorido-{N (1)-phenyl-N (4)-[(pyridin-2-yl-κN)methyl-idene]benzene-1,4-di-amine-κN (4)}mercury(II)).

Project description:The whole mol-ecule of the title complex, [Hg2Cl4(C18H15N3)2], is generated by inversion symmetry. It was synthesized from the pyridine-derived Schiff base N-phenyl-N'-[(pyridin-2-yl)methyl-idene]benzene-1,4-di-amine (PPMBD). The five-coordinated Hg(2+) ions have a distorted square-pyramidal environment defined by two N atoms, viz. the imine and the other pyridyl [Hg-N = 2.467 (6) and 2.310 (6) Å, respectively] belonging to the bidentate imino-pyridine ligand, and three Cl atoms [Hg-Cl = 2.407 (2), 2.447 (2) and 3.031 (2) Å]. The longest Hg-Cl bond is bridging about the inversion centre. In the ligand, the central ring and pyridine ring are oriented at a dihedral angle of 8.1 (4)°, while the planes of the pyridine ring and the terminal phenyl ring are oriented at a dihedral angle of 53.8 (4)°. In the crystal, mol-ecules are linked by N-H⋯Cl and C-H⋯Cl hydrogen bonds, forming sheets parallel to (001).

| S-EPMC4555402 | biostudies-literature

Di-μ-chlorido-bis-{chlorido[4-nitro-N-(pyridin-2-yl-methyl-idene-κN)aniline-κN]mercury(II)}.

Project description:In the centrosymmetric dinuclear title complex, [Hg(2)Cl(4)(C(12)H(9)N(3)O(2))(2)], the Hg(II) ion is in a distorted square-pyramidal coordination environment formed by the N atoms of the diimine ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

| S-EPMC3051965 | biostudies-literature

(2,2'-Bipyridyl-κN,N')bis-(N-butyl-N-methyl-dithio-carbamato-κS,S')cadmium(II).

Project description:The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa-coordinated by two dithio-carbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl mol-ecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N(2)S(4) donor set. Supra-molecular chains, aligned along the a-axis direction, are mediated by C-H⋯S inter-actions and these are connected into layers that stack along the c axis via π-π inter-actions [Cg(pyrid-yl)⋯Cg(pyrid-yl) = 3.6587 (13) Å].

| S-EPMC3052129 | biostudies-literature

Chlorido[1,1'-(5-methyl-1,3-phenyl-ene)bis-(3,5-dimethyl-1H-imidazol-2-yl-idene)]platinum(II).

Project description:In the title compound, [Pt(C17H19N4)Cl], the Pt(II) cation is C,C',C''-chelated by the 1,1'-(5-methyl-1,3-phenyl-ene)bis-(3,5-dimethyl-1H-imidazolyl-idene) anion and coordinated by a Cl(-) anion in a distorted square-planar coordination geometry. ?-? stacking is observed between nearly parallel imidazole and benzene rings of adjacent mol-ecules, the centroid-centroid distance being 3.802?(4)?Å.

| S-EPMC3629494 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data