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Chlorido[6-phenyl-4-(p-tol-yl)-2,2'-bipyridyl-κN,N']platinum(II).

ABSTRACT: The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent mol-ecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short inter-molecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC(3) and PtN(2)C(2) rings, respectively, indicate the existence of π-π inter-actions, which link the mol-ecules into stacks along the a axis. The crystal structure is further stabilized by weak C-H⋯π inter-actions.

SUBMITTER: Lu HB

PROVIDER: S-EPMC2961937 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Chlorido[6-phenyl-4-(p-tol-yl)-2,2'-bipyridyl-κN,N']platinum(II).

Lu Hong Bo HB Lv Guo Qiang GQ Zuo Jin Lin JL Yang Jia Xiang JX

Acta crystallographica. Section E, Structure reports online 20080709 Pt 8

The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent mol-ecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short inter-molecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC(3) and PtN(2)C(2) rings, respectively, indicate the existence of π-π inter-actions, which link the mol-ecules into stacks along the a axis. The crystal structure is further stabilized by w ...[more]

PMID: 21203007

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