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[2-(Phenyl-diazen-yl)pyrrolato]bis(2-pyridylphen-yl)iridium(III).

ABSTRACT: In the title compound, [Ir(C(10)H(8)N(3))(C(11)H(8)N)(2)], the Ir center is octa-hedrally coordinated by the three chelating ligands, with two cyclo-metalated 2-pyridylphenyl ligands [Ir-N = 2.049?(5) and 2.030?(5)?Å; Ir-C = 2.016?(6) and 2.012?(6)?Å] and a bidentate 2-(phenyl-diazen-yl)pyrrolate ligand [Ir-N = 2.204?(5) and 2.079?(5)?Å]. The Ir-N(diazen-yl) bond is longer than the Ir-N(pyrrolate) bond. The structure is stabilized by aromatic ?-? stacking, the shortest parallel distance between ring centroids being 3.426?(8)?Å..

SUBMITTER: Li WY

PROVIDER: S-EPMC2960816 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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