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?-Hydroxido-bis-[(2,2'-bipyridine)tricarbonyl-rhenium(I)] perrhenate.

ABSTRACT: The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa-hedral environment, whereas the Re(VII) atoms show the typical tetra-hedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3?(7)°.

SUBMITTER: Ruth K

PROVIDER: S-EPMC2960830 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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μ-Hydroxido-bis-[(2,2'-bipyridine)tricarbonyl-rhenium(I)] perrhenate.

Ruth Kai K Morawitz Thorsten T Lerner Hans-Wolfram HW Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20080227 Pt 3

The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa-hedral environment, whereas the Re(VII) atoms show the typical tetra-hedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3 (7)°. ...[more]

PMID: 21201878

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