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Dichloridobis(methyl-amine-?N)boron(III) chloride.

ABSTRACT: The title compound, C(2)H(10)BCl(2)N(2) (+)·Cl(-) or [BCl(2)(H(3)CNH(2))(2)](+)·Cl(-), is the first crystallographically characterized di(alkyl-amine)-BCl(2) (+) salt. The B atom is tetra-hedrally coordinated by two Cl and two methyl-amine N atoms. In the crystal structure, the cations and anions inter-act via N-H?Cl hydrogen bonds (mean H?Cl = 2.40?Å), resulting in a layered structure.

SUBMITTER: Weinmann M

PROVIDER: S-EPMC2960873 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Dichloridobis(methyl-amine-κN)boron(III) chloride.

Weinmann Markus M Nuss Jürgen J Jansen Martin M

Acta crystallographica. Section E, Structure reports online 20080213 Pt 3

The title compound, C(2)H(10)BCl(2)N(2) (+)·Cl(-) or [BCl(2)(H(3)CNH(2))(2)](+)·Cl(-), is the first crystallographically characterized di(alkyl-amine)-BCl(2) (+) salt. The B atom is tetra-hedrally coordinated by two Cl and two methyl-amine N atoms. In the crystal structure, the cations and anions inter-act via N-H⋯Cl hydrogen bonds (mean H⋯Cl = 2.40 Å), resulting in a layered structure. ...[more]

PMID: 21201922

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