Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tris(3-methyl-anilinium) penta-chlorido-anti-monate(III) chloride.

ABSTRACT: In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319?(14)?Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H?Cl hydrogen bonds.

SUBMITTER: Liu ML

PROVIDER: S-EPMC3238716 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Tris(3-methyl-anilinium) penta-chlorido-anti-monate(III) chloride.

Liu Ming-Liang ML

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H⋯Cl hydrogen bonds. ...[more]

PMID: 22199593

Similar Datasets

Tris(4-methyl-anilinium) penta-chlorido-anti-monate(III) chloride monohydrate.

Project description:The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl-anilinium cations, Cl(-) and [SbCl(5)](2-) anions and water mol-ecules. The five Cl atoms bound to Sb [Sb-Cl = 2.4043?(9)-2.6262?(11)?Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2-) anions related by an inversion center are joined by Sb?Cl inter-actions [Sb?Cl = 3.7273?(14)?Å] into an [Sb(2)Cl(10)](4-) dimer with two bridging Cl atoms. The anions, water mol-ecules and ammonium groups of the cations are linked by N-H?Cl, N-H?O and O-H?Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methyl-anilinium cations are packed between these layers.

| S-EPMC3343837 | biostudies-other

Bis(2-methyl-piperidinium) penta-chlorido-anti-monate(III).

Project description:The asymmetric unit of the title compound, (C(6)H(14)N)(2)[SbCl(5)], contains one cation and half of the anion on a special position (specifically, the Sb(III) ion and three chloride anions are situated on a mirror plane). In the [SbCl(5)](2-) unit, the Sb(III) ion is coordinated by five chloride anions [Sb-Cl = 2.3721?(11)-2.6656?(12)?Å] in a distorted square-pyramidal geometry. However, one chloride anion from a neighbouring [SbCl(5)](2-) unit provides a short Sb?Cl contact of 3.3600?(12)?Å and completes the Sb coordination environment up to an elongated octa-hedron. In the crystal, N-H?Cl hydrogen bonds link cations and anions into columns propagating along [100].

| S-EPMC3344392 | biostudies-literature

Tris(N,N-di-methyl-anilinium) tri-?-bromido-bis[tribromido-anti-monate(III)].

Project description:In the title compound, (C8H12N)3[Sb2Br9], two of the three unique N,N-dimethyanilinium cations exhibit flip-flop disorder with an occupancy ratio of 0.58?(1):0.42?(1). N-H?Br hydrogen bonds link the organic cations and bioctahedral face-sharing anions into a three-dimensional network.

| S-EPMC3772401 | biostudies-literature

Tris(3-methyl-anilinium) tetra-chlorido-zincate chloride hemihydrate.

Project description:The asymmetric unit of the title compound, (C(7)H(10)N)(3)[ZnCl(4)]Cl·0.5H(2)O, consists of three 3-methyl-anilinium cations, one tetrahedral tetra-chloridozincate anion and one chloride anion and a water mol-ecule, which lies on a twofold axis. The components are linked into chains parallel to the a axis by N-H⋯Cl hydrogen bonds.

| S-EPMC3247542 | biostudies-literature

N-Methyl-piperazinediium penta-chloridoanti-monate(III) monohydrate.

Project description:The asymmetric unit of the title compound, (C(5)H(14)N(2))[SbCl(5)]·H(2)O, consists of an N-methyl-piperazinediium cation, a penta-chloridoanti-monate anion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment, and one solvent water mol-ecule. The crystal structure is stabilized by inter-molecular N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds.

| S-EPMC2915089 | biostudies-literature

catena-Poly[bis(1,3-benzo-thia-zol-3-ium) [[di-chlorido-anti-monate(III)]-di-μ-chlorido-μ-oxido-[chlorido-anti-monate(III)]-μ-chlorido]].

Project description:The title compound, {(C7H6NS)2[Sb2Cl6O]} n , contains two benzo-thia-zolidium cations and one tri-μ-chlorido-tri-chlorido-μ-oxido-di-anti-monate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra, i.e. a square-pyramidal SbCl4O and a distorted octa-hedral SbOCl5 unit, sharing a common face (comprising the O atom and two Cl atoms). The two benzo-thia-zole cations are quasi-planar and subtend a dihedral angle of 19.93 (5)°. The crystal packing can be described by alternating (100) layers and [001] chains of the organic cations and inorganic anions connected through an extensive three-dimensional network of N-H⋯Cl, C-H⋯O and C-H⋯Cl hydrogen bonds. This is consolidated by slipped π-π stacking, with centroid-to-centroid distances between the benzo-thia-zole rings of 3.7111 (18)-3.8452 (16) Å. These inter-actions link the mol-ecules within the layers and also link the layers together and reinforce the cohesion of the ionic structure.

| S-EPMC4770971 | biostudies-literature

Octa-kis(3-methyl-anilinium) hexa-chlorido-cadmate tetra-chloride.

Project description:The asymmetric unit of the title compound, (C(7)H(10)N)(8)[CdCl(6)]Cl(4), contains four 3-methyl-anilinium cations, two chloride anions and half an octa-hedral hexa-chloridocadmate(II) anion, which lies on an inversion centre. In the crystal, numerous N-H?Cl and bifurcated N-H?(Cl,Cl) hydrogen bonds link the components.

| S-EPMC3238727 | biostudies-literature

Dimorpholinium penta-chloridoanti-monate(III).

Project description:The asymmetric unit of the title compound, (C(4)H(10)NO)(2)[SbCl(5)], consists of two morpholinium cations in chair conformations, and a penta-chloridoanti-monate dianion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment. The morpholinium cations are connected to each other by N-H⋯O hydrogen bonds, and they link the chloride anions and the anti-monate SbCl(3) group via N-H⋯Cl contacts.

| S-EPMC2969790 | biostudies-literature

Diisonicotinium penta-chloridoanti-monate(III) monohydrate.

Project description:In the title compound, (C(6)H(6)NO(2))(2)[SbCl(5)]·H(2)O, the Sb(III) atom exhibits a distorted square-pyramidal coordination geometry. The crystal structure is stabilized by inter-molecular N-H⋯Cl, N-H⋯O, O-H⋯Cl and O-H⋯O hydrogen bonds, forming an extended three-dimensional network.

| S-EPMC2969829 | biostudies-literature

(R)-2-Methyl-piperazine-1,4-diium tetra-chloridoanti-monate(III) chloride.

Project description:In the complex anion of the title compound, (C(5)H(14)N(2))[SbCl(4)]Cl, the Sb atom is tetra-coordinate within a saw-horse configuration. The cation adopts a chair conformation. The crystal structure is stabilized by inter-molecular N-H?Cl hydrogen bonds.

| S-EPMC3011473 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data