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Tris(3-methyl-anilinium) penta-chlorido-anti-monate(III) chloride.

ABSTRACT: In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319?(14)?Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H?Cl hydrogen bonds.

SUBMITTER: Liu ML

PROVIDER: S-EPMC3238716 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Tris(3-methyl-anilinium) penta-chlorido-anti-monate(III) chloride.

Liu Ming-Liang ML

Acta crystallographica. Section E, Structure reports online 20111123 Pt 12

In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H⋯Cl hydrogen bonds. ...[more]

PMID: 22199593

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