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(1-Acetyl-2,6-diphenyl-piperidin-4-yl-idene)(phen-yl)acetonitrile.

ABSTRACT: In the title mol-ecule, C(27)H(24)N(2)O, the piperidine ring adopts a boat conformation. The acetyl group at position 1 has a bis-ectional orientation. The two phenyl rings attached to the piperidine ring at positions 2 and 6 have bis-ectional and axial orientations, respectively, and make a dihedral angle of 75.27?(10)°. The phenyl-acetonitrile group at position 4 has an equatorial orientation. Mol-ecules are linked by C-H?N, C-H?O inter-molecular and C-H?? inter-actions. A C-H?O intra-molecular inter-action is also found in the mol-ecule.

SUBMITTER: Manimekalai A

PROVIDER: S-EPMC2961162 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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(1-Acetyl-2,6-diphenyl-piperidin-4-yl-idene)(phen-yl)acetonitrile.

Manimekalai A A Balamurugan A A Balamurugan S S Thiruvalluvar A A Butcher R J RJ

Acta crystallographica. Section E, Structure reports online 20080404 Pt 5

In the title mol-ecule, C(27)H(24)N(2)O, the piperidine ring adopts a boat conformation. The acetyl group at position 1 has a bis-ectional orientation. The two phenyl rings attached to the piperidine ring at positions 2 and 6 have bis-ectional and axial orientations, respectively, and make a dihedral angle of 75.27 (10)°. The phenyl-acetonitrile group at position 4 has an equatorial orientation. Mol-ecules are linked by C-H⋯N, C-H⋯O inter-molecular and C-H⋯π inter-actions. A C-H⋯O intra-molecula ...[more]

PMID: 21202289

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