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Hexaaqua-nickel(II) bis-[4-(2-hydroxy-benzyl-ideneamino)benzene-sulfonate].

ABSTRACT: In the title compound, [Ni(H(2)O)(6)](C((C(13) )H(10)NO(4)S)(2), the nickel(II) atom, lying on a center of symmetry, is six-coordinated by six aqua O-atom donors. The dihedral angle between the two benzene rings is 33.1?(3)°. The crystal structure is stabilized by aqua-anion O-H?O hydrogen bonds. Intra-molecular O-H?N and C-H?O hydrogen-bonding inter-actions occur in the anion.

SUBMITTER: Tai XS

PROVIDER: S-EPMC2961879 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Hexaaqua-nickel(II) bis-[4-(2-hydroxy-benzyl-ideneamino)benzene-sulfonate].

Tai Xi-Shi XS Xu Jun J Feng Yi-Min YM Liang Zu-Pei ZP

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the title compound, [Ni(H(2)O)(6)](C((C(13) )H(10)NO(4)S)(2), the nickel(II) atom, lying on a center of symmetry, is six-coordinated by six aqua O-atom donors. The dihedral angle between the two benzene rings is 33.1 (3)°. The crystal structure is stabilized by aqua-anion O-H⋯O hydrogen bonds. Intra-molecular O-H⋯N and C-H⋯O hydrogen-bonding inter-actions occur in the anion. ...[more]

PMID: 21202759

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