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Bis(N,N-dimethyl-formamide-?O)bis-(2,4,6-trinitro-phenolato-?O,O)copper(II).

ABSTRACT: The mol-ecule of the title complex, [Cu(C(6)H(2)N(3)O(7))(2)(C(3)H(7)NO)(2)], is disposed about a crystallographic centre of symmetry. The Cu(II) cation is six-coordinated by two phenolate O atoms and two ortho-nitro O atoms of two picrate units and by two carbonyl O atoms from two coordinated dimethyl-formamide mol-ecules, forming a distorted octa-hedral geometry.

SUBMITTER: Li BY

PROVIDER: S-EPMC2967846 | biostudies-other | 2008 Dec

REPOSITORIES: biostudies-other

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Bis(N,N-dimethyl-formamide-κO)bis-(2,4,6-trinitro-phenolato-κO,O)copper(II).

Li Bai-Yu BY Tong Jun-Feng JF Dong Wen-Kui WK Yao Jian J Wu Jian-Chao JC

Acta crystallographica. Section E, Structure reports online 20081203 Pt 1

The mol-ecule of the title complex, [Cu(C(6)H(2)N(3)O(7))(2)(C(3)H(7)NO)(2)], is disposed about a crystallographic centre of symmetry. The Cu(II) cation is six-coordinated by two phenolate O atoms and two ortho-nitro O atoms of two picrate units and by two carbonyl O atoms from two coordinated dimethyl-formamide mol-ecules, forming a distorted octa-hedral geometry. ...[more]

PMID: 21581467

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