Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tris(O-cyclo-hexyl dithio-carbonato-?S)anti-mony(III).

ABSTRACT: In the mol-ecule of the title compound, [Sb(C(7)H(11)OS(2))(3)], the anti-mony(III) is coordinated by the S atoms of three O-alkyl xanthate groups acting as monodentate ligands, forming a distorted trigonal-pyramidal coordination.

SUBMITTER: Li W

PROVIDER: S-EPMC2967878 | biostudies-other | 2008

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Tris(O-cyclo-hexyl dithio-carbonato-κS)anti-mony(III).

Li Wenkuan W Yin Handong H Wen Liyuan L Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

In the mol-ecule of the title compound, [Sb(C(7)H(11)OS(2))(3)], the anti-mony(III) is coordinated by the S atoms of three O-alkyl xanthate groups acting as monodentate ligands, forming a distorted trigonal-pyramidal coordination. ...[more]

PMID: 21581504

Similar Datasets

Redetermination of tris-(N,N-diethyl-dithio-carbamato)anti-mony(III).

Project description:The title compound, [Sb(C(5)H(10)NS(2))(3)], was synthesized from Sb(2)O(3), diethyl-amine, carbon dis-ulfide, hydro-chloric acid and sodium hydroxide. The structure has been published previously but H atoms were not included in the model [Raston & White (1976 ?). Chem. Soc. Dalton Trans. p. 791]. The current determination has significantly higher precision than the original work. The complex has three ligands. The Sb atom is coordinated by three bidentate diethyl-dithio-carbamate groups, two in an almost planar fashion and the third perpendicular to that plane with a dihedral angle of 86.429?(13)°. One ethyl group is disordered over two positions of equal occupancy.

| S-EPMC2968436 | biostudies-other

Tris(?-cyclo-penta-dien-yl)hafnium(III).

Project description:In the crystal structure of the title compound, [Hf(C(5)H(5))(3)], three cyclo-penta-dienyl ligands surround the Hf(III) atom in a trigonal-planar geometry. The mol-ecule lies on a sixfold inversion axis.

| S-EPMC3089176 | biostudies-literature

Di-n-butyl-bis-(N-cyclo-hexyl-N-ethyl-dithio-carbamato-?S,S')tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(9)H(16)NS(2))(2)], is chelated by the two dithio-carbamate ions in a six-coordinate skew-trapezoidal-bipyramidal geometry. The two butyl groups are disordered over two positions in a 1:1 ratio.

| S-EPMC3007498 | biostudies-literature

Tris[bis-(2-methyl-prop-yl)dithio-phosphinato]bis-muth(III).

Project description:The title compound, [Bi(C(8)H(18)PS(2))(3)], contains a Bi(III) cation surrounded by three bis-(2-methyl-prop-yl)dithio-phosphinate anions, leading to a distorted octa-hedral coordination for the heavy metal. The Bi-S and S-P bond lengths are in the ranges 2.7694?(18)-2.8391?(17) and 2.019?(2)-2.035?(2)?Å, respectively. The crystal structure is consolidated by C-H?S hydrogen bonds. Intra-molecular C-H?? inter-actions also play a role in stabilizing the mol-ecules.

| S-EPMC2979605 | biostudies-literature

Acetonitrile-trichloridobis(cyclo-hexyl-diphenyl-phosphane)rhodium(III) acetonitrile disolvate.

Project description:In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol-ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol-ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol-ecule in a distorted octa-hedral geometry. Intra-molecular C-H?Cl inter-actions are observed. The uncoordinated acetonitrile mol-ecule is disordered over two sites with occupancies of 0.588?(4) and 0.412?(4).

| S-EPMC3238697 | biostudies-literature

Chloridobis{2-[(dimethyl-amino)-meth-yl]phen-yl}anti-mony(III).

Project description:In the title compound, [Sb(C(9)H(12)N)(2)Cl], the Sb atom adopts a Ψ-trigonal-bipyramidal geometry. The two 2-[(dimethyl-amino)-methyl]-phenyl ligands are coordinated asymmetrically to the Sb atom. The carbon atoms of one of the ligands are disordered over sets of sites with equal occupancy, resulting in two conformational isomers in the crystal. The Sb-C and Sb-N distances in the ordered ligand are: 2.153 (4) and 3.326 (5) Å, respectively. The corresponding distances in the disordered ligand are: 2.103 (5)/2.188 (5) and 2.454 (3) Å, respectively. The structure displays intra-molecular C-H⋯Cl hydrogen bonding.

| S-EPMC2970968 | biostudies-literature

N-Cyclo-hexyl-cyclo-hexa-naminium chloride.

Project description:In the title salt, C(12)H(24)N(+)·Cl(-), both cyclo-hexyl rings adopt chair conformations and the NH(2) unit is situated in the equatorial position with respect to the rings in the cation. The large C-N-C bond angle [117.99 (14)°] in the cation is a result of linking two bulky cyclo-hexyl rings to the N atom. The aminium H atoms are involved in inter-molecular N-H⋯Cl hydrogen bonds, forming an infinite zigzag chain parallel to the c axis. The crystal studied was a racemic twin with a twin fraction of 0.28 (18).

| S-EPMC3051479 | biostudies-literature

2-Isopropyl-5-methyl-cyclo-hexyl N-cyclo-hexyl-P-phenyl-phospho-namidate.

Project description:The title compound, C(22)H(36)NO(2)P, features a P atom bonded to a phenyl ring, a cyclo-hexyl-amine unit and the O atom of a menthyl group. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds connect mol-ecules into a one-dimensional chain in the b direction.

| S-EPMC3007901 | biostudies-literature

N'-Cyclo-hexyl-idenebenzohydrazide.

Project description:In the title compound, C(13)H(16)N(2)O, the cyclo-hexane ring adopts a chair conformation. In the crystal structure, inter-molecular N-H?O and C-H?O hydrogen bonds link the mol-ecules into chains propagating in [001].

| S-EPMC2980044 | biostudies-literature

Cyclo-hexyl-ammonium nitrate.

Project description:In the title salt, C6H14N(+)·NO3 (-), the cyclo-hexyl ring adopts a chair conformation. The ammonium group occupies an equatorial position and the crystal struture is stabilized by inter-molecular N-H⋯O hydrogen-bonding inter-actions, resulting in a three-dimensional network.

| S-EPMC3998418 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data