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[Bis(3-phenyl-prop-2-enyl-idene)propane-1,3-diamine-?N,N']dibromidocobalt(II).

ABSTRACT: In the crystal structure of the title compound, [CoBr(2)(C(21)H(22)N(2))], the Co(II) atom is four-coordinated by two bromide anions and two N atoms from the bidentate Schiff base ligand in a distorted tetra-hedral geometry.

SUBMITTER: Montazerozohori M

PROVIDER: S-EPMC2967899 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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[Bis(3-phenyl-prop-2-enyl-idene)propane-1,3-diamine-κN,N']dibromidocobalt(II).

Montazerozohori M M Habibi M H MH Amirnasr M M Saharin Siti Munirah SM Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20081213 Pt 1

In the crystal structure of the title compound, [CoBr(2)(C(21)H(22)N(2))], the Co(II) atom is four-coordinated by two bromide anions and two N atoms from the bidentate Schiff base ligand in a distorted tetra-hedral geometry. ...[more]

PMID: 21581526

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Project description:The title compound, C(19)H(20)Cl(2)N(2), is a potential bidentate Schiff base ligand. Intra-molecular C-H⋯N hydrogen bonds form five-membered rings, generating S(5) ring motifs. Each imino functional group is coplanar with its adjacent benzene ring; the two benzene rings form a dihedral angle of 51.30 (4)°. An inter-esting feature of the crystal structure is weak inter-molecular Cl⋯Cl [3.4752 (4) Å] and Cl⋯N [3.2927 (9) Å] inter-actions. Inter-molecular Cl⋯N inter-actions link mol-ecules into dimers with R(2) (2)(22) ring motifs. The crystal structure is further stabilized by weak π-π [centroid-centroid distances = 3.6970 (6)-3.8560 (6) Å] inter-actions.

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