Ontology highlight
ABSTRACT:
SUBMITTER: Wriedt M
PROVIDER: S-EPMC2968858 | biostudies-other | 2009
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20090325 Pt 4
In the crystal structure of the title compound, [Co(NCO)(2)(C(4)H(4)N(2))(2)](n), the Co(II) cation is coordinated by four N-bonded pyrazine ligands and two N-bonded cyanate anions in a slightly distorted octa-hedral geometry. The crystal structure consists of μ-N:N' pyrazine-bridged cobalt cyanate chains; these are further linked by additional μ-N:N'-bridging pyrazine ligands into layers, which are stacked perpendicular to the crystallographic a axis. The C and O atoms in both crystallographic ...[more]