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2,4,8-Trioxa-2-aza-1,3,6(1,2)-tri-benzena-2(2,3)-bicyclo-[3.3.0]octa-na-cyclo-octa-phane.

ABSTRACT: The crystal structure of the title compound, C(26)H(25)NO(3), was determined as part of an investigation of host-guest and electron donor-acceptor complexes. The oxazole and the pyrrole rings both adopt envelope conformations. The dihedral angle between the two benzene rings directly linked to the oxazole ring is 49.5?(1)°. The crystal structure is stabilized by a C-H?? inter-action.

SUBMITTER: Seshadri PR

PROVIDER: S-EPMC2968892 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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2,4,8-Trioxa-2-aza-1,3,6(1,2)-tri-benzena-2(2,3)-bicyclo-[3.3.0]octa-na-cyclo-octa-phane.

Seshadri P R PR Balakrishnan B B Ilangovan K K Purushothaman S S Raghunathan R R

Acta crystallographica. Section E, Structure reports online 20090306 Pt 4

The crystal structure of the title compound, C(26)H(25)NO(3), was determined as part of an investigation of host-guest and electron donor-acceptor complexes. The oxazole and the pyrrole rings both adopt envelope conformations. The dihedral angle between the two benzene rings directly linked to the oxazole ring is 49.5 (1)°. The crystal structure is stabilized by a C-H⋯π inter-action. ...[more]

PMID: 21582414

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