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{2,2'-[6,6'-Dimethoxy-cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O}cobalt(II) monohydrate.

ABSTRACT: In the title complex, [Co(C(22)H(24)N(2)O(4))]·H(2)O, the Co(II) atom is in an almost square-planar coordination environment involv-ing two O and two N atoms from the Schiff base ligand. A water mol-ecule cocrystallizes with the coordination compound and may be held in the crystal by O-H?O hydrogen bonds. Heteroatomic ?-? ring inter-actions may be present between symmetry-related complexes, with centroid-centroid distances of 3.5661?(8)?Å.

SUBMITTER: Bao Y

PROVIDER: S-EPMC2969264 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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{2,2'-[6,6'-Dimethoxy-cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O}cobalt(II) monohydrate.

Bao Yan Y Li Hong-Feng HF Yan Peng-Fei PF Li Guang-Ming GM Hou Guang-Feng GF

Acta crystallographica. Section E, Structure reports online 20090613 Pt 7

In the title complex, [Co(C(22)H(24)N(2)O(4))]·H(2)O, the Co(II) atom is in an almost square-planar coordination environment involv-ing two O and two N atoms from the Schiff base ligand. A water mol-ecule cocrystallizes with the coordination compound and may be held in the crystal by O-H⋯O hydrogen bonds. Heteroatomic π-π ring inter-actions may be present between symmetry-related complexes, with centroid-centroid distances of 3.5661 (8) Å. ...[more]

PMID: 21582700

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