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(?-1,2-Di-4-pyridylethyl-ene-?N:N')bis-[bis-(N,N-dimethyl-dithio-carbamato-?S,S')zinc(II)].

ABSTRACT: The dinuclear title compound, [Zn(2)(C(3)H(6)NS(2))(4)(C(12)H(10)N(2))], features two five-coordinate Zn atoms, one with an NS(4) coordination geometry distorted towards a trigonal-bipyramidal arrangement, and the other distorted towards a square pyramid. In the crystal, mol-ecules are connected into supra-molecular zigzag chains via C-H?S contacts. Chains are connected via C-H?? interactions, consolidating the crystal packing.

SUBMITTER: Poplaukhin P

PROVIDER: S-EPMC2971210 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(μ-1,2-Di-4-pyridylethyl-ene-κN:N')bis-[bis-(N,N-dimethyl-dithio-carbamato-κS,S')zinc(II)].

Poplaukhin Pavel P Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

The dinuclear title compound, [Zn(2)(C(3)H(6)NS(2))(4)(C(12)H(10)N(2))], features two five-coordinate Zn atoms, one with an NS(4) coordination geometry distorted towards a trigonal-bipyramidal arrangement, and the other distorted towards a square pyramid. In the crystal, mol-ecules are connected into supra-molecular zigzag chains via C-H⋯S contacts. Chains are connected via C-H⋯π interactions, consolidating the crystal packing. ...[more]

PMID: 21578197

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