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(?-trans-1,2-Di-4-pyridylethyl-ene-?N:N')bis-[bis-(N,N-diisopropyl-dithio-carbamato-?S,S')zinc(II)].

ABSTRACT: The dinuclear title compound, [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(2))], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithio-carbamate ligands and a pyridine N atom to define an NS(4) coordination geometry tending towards a square pyramid, with the N atom in the apical site. In the crystal structure, C-H?S contacts lead to supra-molecular chains.

SUBMITTER: Arman HD

PROVIDER: S-EPMC2971214 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(μ-trans-1,2-Di-4-pyridylethyl-ene-κN:N')bis-[bis-(N,N-diisopropyl-dithio-carbamato-κS,S')zinc(II)].

Arman Hadi D HD Poplaukhin Pavel P Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

The dinuclear title compound, [Zn(2)(C(7)H(14)NS(2))(4)(C(12)H(10)N(2))], is centrosymmetric about the central C=C bond. The five-coordinate Zn atom is bonded to two asymmetrically chelating dithio-carbamate ligands and a pyridine N atom to define an NS(4) coordination geometry tending towards a square pyramid, with the N atom in the apical site. In the crystal structure, C-H⋯S contacts lead to supra-molecular chains. ...[more]

PMID: 21578198

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μ-1,2-Di-4-pyridylethane-κN:N'-bis-[bis-(N,N-diisopropyl-dithio-carbamato-κS,S')zinc(II)].

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catena-Poly[[bis-(O,O'-diisopropyl dithio-phosphato-?S,S')nickel(II)]-?-bis-(4-pyridylmethyl-ene)diazane-?N:N'].

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