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1,2-Dimethyl-4,5-diphenyl-benzene determined on a Bruker SMART X2S benchtop crystallographic system.

ABSTRACT: The title compound, C(20)H(18), has two crystallographically independent mol-ecules in the asymmetric unit. The phenyl substituents of mol-ecule A are twisted away from the plane defined by the central benzene ring by 131.8?(2) and -52.7?(3)°. The phenyl substituents of mol-ecule B are twisted by -133.3?(2) and 50.9?(3)°. Each mol-ecule is stabilized by a pair of intra-molecular C(aryl, sp(2))-H?? inter-actions, as well as by several inter-molecular C(methyl, sp(3))-H?? inter-actions.

SUBMITTER: Briggs JB 

PROVIDER: S-EPMC2977836 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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1,2-Dimethyl-4,5-diphenyl-benzene determined on a Bruker SMART X2S benchtop crystallographic system.

Briggs Jonathan B JB   Jazdzyk Mikaël D MD   Miller Glen P GP  

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The title compound, C(20)H(18), has two crystallographically independent mol-ecules in the asymmetric unit. The phenyl substituents of mol-ecule A are twisted away from the plane defined by the central benzene ring by 131.8 (2) and -52.7 (3)°. The phenyl substituents of mol-ecule B are twisted by -133.3 (2) and 50.9 (3)°. Each mol-ecule is stabilized by a pair of intra-molecular C(aryl, sp(2))-H⋯π inter-actions, as well as by several inter-molecular C(methyl, sp(3))-H⋯π inter-actions. ...[more]

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