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1,3,5,7-Tetra-kis(4-iodo-phen-yl)adamantane benzene tetra-solvate.

ABSTRACT: The title mol-ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic symmetry and crystallizes with four symmetry-related benzene solvent mol-ecules. The phenyl group is eclipsed with one of the adamantane C-C bonds. The tetra-phenyl-adamantane units and the benzene solvent mol-ecules are connected by weak inter-molecular phen-yl-benzene C-H?? and benzene-benzene C-H?? inter-actions. In the crystal, mol-ecules are linked along the c-axis direction via the iodo-phenyl groups by a combination of weak inter-molecular I?I [3.944?(1)?Å] and I??(phen-yl) [3.608?(6) and 3.692?(5)?Å] inter-actions.

SUBMITTER: Bats JW

PROVIDER: S-EPMC3006832 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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1,3,5,7-Tetra-kis(4-iodo-phen-yl)adamantane benzene tetra-solvate.

Bats Jan W JW Pospiech Steffen S Prisner Thomas F TF

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

The title mol-ecule, C(34)H(28)I(4)·4C(6)H(6), has crystallographic symmetry and crystallizes with four symmetry-related benzene solvent mol-ecules. The phenyl group is eclipsed with one of the adamantane C-C bonds. The tetra-phenyl-adamantane units and the benzene solvent mol-ecules are connected by weak inter-molecular phen-yl-benzene C-H⋯π and benzene-benzene C-H⋯π inter-actions. In the crystal, mol-ecules are linked along the c-axis direction via the iodo-phenyl groups by a combination of we ...[more]

PMID: 21587865

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