Unknown

Dataset Information

0

Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)manganese(II) 3.5-hydrate.

ABSTRACT: In the title complex, [Mn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Mn(II) cation is six-coordinated by two N,O-bidentate H(2)pimda(-) ligands (H(2)pimda(-) = 5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ate) and two water mol-ecules in a distorted octa-hedral environment. The complete solid-state structure can be described as a three-dimensional supra-molecular framework stabilized by a wide range of O-H?O and N-H?O hydrogen bonds. The propyl groups of H(2)pimda(-) are disordered over two sets of sites with refined occupancies of 0.759?(5):0.241?(5) and 0.545?(7):0.455?(7).

SUBMITTER: Li SJ 

PROVIDER: S-EPMC3007852 | biostudies-other | 2010

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O)manganese(II) 3.5-hydrate.

Li Shi-Jie SJ   Miao Dong-Liang DL   Song Wen-Dong WD   Li Shi-Hong SH   Yan Jian-Bin JB  

Acta crystallographica. Section E, Structure reports online 20100818 Pt 9

In the title complex, [Mn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Mn(II) cation is six-coordinated by two N,O-bidentate H(2)pimda(-) ligands (H(2)pimda(-) = 5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ate) and two water mol-ecules in a distorted octa-hedral environment. The complete solid-state structure can be described as a three-dimensional supra-molecular framework stabilized by a wide range of O-H⋯O and N-H⋯O hydrogen bonds. The propyl groups of H(2)pimda(-) are disordered over two se  ...[more]

Similar Datasets

Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)cobalt(II) 3.5-hydrate.
| S-EPMC3050148 | biostudies-literature
Unknown Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)magnesium(II) 3.5-hydrate.
| S-EPMC2983537 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)zinc(II) 3.5-hydrate.
| S-EPMC3008058 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)cadmium(II) 3.5-hydrate.
| S-EPMC3007830 | biostudies-other
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)nickel(II) tetra-hydrate.
| S-EPMC3007488 | biostudies-literature
Unknown Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)manganese(II) N,N-dimethyl-formamide disolvate.
| S-EPMC2980198 | biostudies-literature
Unknown Poly[diaqua-bis(?-4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-?N,O:O)calcium(II)].
| S-EPMC2980060 | biostudies-literature
Unknown trans-Diaqua-bis[5-carb-oxy-2-(3-pyridyl)-1H-imidazole-4-carboxyl-ato-?N,O]manganese(II).
| S-EPMC2959396 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)cadmium N,N-dimethyl-formamide disolvate.
| S-EPMC3238758 | biostudies-literature
Unknown Poly[diaqua-bis(μ(2)-5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O:O)lead(II)].
| S-EPMC2979092 | biostudies-literature