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(Acetyl-acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate.

ABSTRACT: In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl-acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand. The dicyanamide N atoms are each involved in hydrogen bonds to water mol-ecules. There are also hydrogen bonds between both the water mol-ecules and their centrosymmetric pairs, creating a hydrogen-bonded chain along the b-axis direction.

SUBMITTER: Janani H

PROVIDER: S-EPMC3007884 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(Acetyl-acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate.

Janani Halimeh H Rezvani Ali Reza AR Rostami-Charati Faramarz F Makha Mohamed M Skelton Brian W BW

Acta crystallographica. Section E, Structure reports online 20100804 Pt 9

In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl-acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand. The dicyanamide N atoms are each involved in hydrogen bonds to water mol-ecules. There are also hydrogen bonds between both the water mol-ecules and their centrosymmetric pairs, creating a hydrogen-bo ...[more]

PMID: 21588486

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