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2-Chloro-N'-[4-(dimethyl-amino)-benzyl-idene]-N-[4-(3-methyl-3-phenyl-cyclo-but-yl)-1,3-thia-zol-2-yl]acetohydrazide.

ABSTRACT: The mol-ecular conformation of the title compound, C(25)H(27)ClN(4)OS, is stabilized by an intra-molecular benzyl-idine C-H?N(thia-zole) hydrogen bond. The thiazole ring makes dihedral angles of 12.0?(3) and 20.4?(2)°, respectively, with the phenyl and benzene rings, while the phenyl and benzene rings make a dihedral angle of 22.6?(2)°. The crystal packing involves weak inter-molecular thia-zole C-H?O(carbon-yl) and methyl C-H?? hydrogen-bonding associations.

SUBMITTER: Inkaya E

PROVIDER: S-EPMC3050246 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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2-Chloro-N'-[4-(dimethyl-amino)-benzyl-idene]-N-[4-(3-methyl-3-phenyl-cyclo-but-yl)-1,3-thia-zol-2-yl]acetohydrazide.

Inkaya Ersin E Dinçer Muharrem M Cukurovalı Alaaddin A Yılmaz Engin E

Acta crystallographica. Section E, Structure reports online 20101215 Pt 1

The mol-ecular conformation of the title compound, C(25)H(27)ClN(4)OS, is stabilized by an intra-molecular benzyl-idine C-H⋯N(thia-zole) hydrogen bond. The thiazole ring makes dihedral angles of 12.0 (3) and 20.4 (2)°, respectively, with the phenyl and benzene rings, while the phenyl and benzene rings make a dihedral angle of 22.6 (2)°. The crystal packing involves weak inter-molecular thia-zole C-H⋯O(carbon-yl) and methyl C-H⋯π hydrogen-bonding associations. ...[more]

PMID: 21522642

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