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Chlorido{N-[(diethyl-amino)-dimethyl-sil-yl]anilido-?N}(N,N,N',N'-tetra-methyl-ethane-1,2-diamine-?N,N')cobalt(II).

ABSTRACT: In the title cobalt(II) compound, [Co(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the ethane-1,2-diamine donor mol-ecule coordin-ates the metal atom in an N,N'-chelating mode, with Co-N distances of 2.136?(2) and 2.140?(3)?Å. An anilide ligand connects to the Co(II) atom with a ?-bond, the Co-N(anilide) distance being 1.931?(2)?Å. The four-coordinate Co(II) atom demonstrates a slightly distorted tetra-hedral geometry.

SUBMITTER: Bai SD

PROVIDER: S-EPMC3051766 | biostudies-other | 2011

REPOSITORIES: biostudies-other

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Chlorido{N-[(diethyl-amino)-dimethyl-sil-yl]anilido-κN}(N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κN,N')cobalt(II).

Bai Sheng-Di SD Hu Min M

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

In the title cobalt(II) compound, [Co(C(12)H(21)N(2)Si)Cl(C(6)H(16)N(2))], the ethane-1,2-diamine donor mol-ecule coordin-ates the metal atom in an N,N'-chelating mode, with Co-N distances of 2.136 (2) and 2.140 (3) Å. An anilide ligand connects to the Co(II) atom with a σ-bond, the Co-N(anilide) distance being 1.931 (2) Å. The four-coordinate Co(II) atom demonstrates a slightly distorted tetra-hedral geometry. ...[more]

PMID: 21522921

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