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6-Phenyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl perchlorate.

ABSTRACT: In the title compound, [Bi(C(20)H(17)N)(ClO(4))] or C(20)H(17)BiClNO(4), the Bi(III) ion assumes a distorted ? trigonal-bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak inter-molecular C-H?O hydrogen bonding is present in the crystal structure.

SUBMITTER: Zhang XW

PROVIDER: S-EPMC3151844 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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6-Phenyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl perchlorate.

Zhang Xiao-Wen XW Fan Ting T

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the title compound, [Bi(C(20)H(17)N)(ClO(4))] or C(20)H(17)BiClNO(4), the Bi(III) ion assumes a distorted ψ trigonal-bipyramidal geometry, with two C atoms and the electron lone pair of the Bi atom at the equatorial positions and an amine N atom and a perchlorate O atom at the apical positions. Weak inter-molecular C-H⋯O hydrogen bonding is present in the crystal structure. ...[more]

PMID: 21836870

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