Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide.

ABSTRACT: The title compound, C(16)H(21)NP(+)·I(-), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P-N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98?(5)°. A weak donor-acceptor N-H?I inter-action is observed.

SUBMITTER: Peulecke N

PROVIDER: S-EPMC3151846 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

(Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide.

Peulecke Normen N Peitz Stephan S Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

The title compound, C(16)H(21)NP(+)·I(-), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P-N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor-acceptor N-H⋯I inter-action is observed. ...[more]

PMID: 21837129

Similar Datasets

(2-Amino-phen-yl)methyl-diphenyl-phospho-nium iodide.

Project description:The asymmetric unit of the title compound, C(19)H(19)NP(+)·I(-), contains two tetra-alkyl-phospho-nium cations and two I(-) anions. The P atoms are four-coordinated in distorted tetra-hedral configurations by three phenyl and one methyl C atoms. There are weak intra- and inter-molecular N-H?I contacts.

| S-EPMC2959292 | biostudies-literature

(Cyano-meth-yl)triphenyl-phospho-nium chloride.

Project description:In the mol-ecule of the title compound, C(20)H(17)NP(+)·Cl(-), the coordination around the P atom is slightly distorted tetra-hedral. In the crystal structure, inter-molecular C-H⋯N and C-H⋯Cl hydrogen bonds link the mol-ecules. There is a π-π contact between the phenyl rings [centroid-centroid distance = 3.702 (3) Å].

| S-EPMC2959552 | biostudies-literature

Diethyl [benzyl-amino-(1,3-diphenyl-1H-pyrazol-4--yl)meth-yl]phospho-nate.

Project description:In the title compound, C(27)H(30)N(3)O(3)P, the pyrazole ring is essentially planar [maximum deviation = 0.002 (2) Å] and it forms dihedral angles of 9.3 (1) and 40.2 (1)°, respectively, with the phenyl rings attached to the N and C atoms. In the crystal, pairs of centrosymmetrically related mol-ecules are linked into dimers by N-H⋯O hydrogen bonds.

| S-EPMC3200952 | biostudies-literature

[(4-Dimethyl-amino-2-methyl-5-phenyl-furan-3-yl)meth-yl]diethyl-methyl-aza-nium iodide.

Project description:In the title compound, C(19)H(29)N(2)O(+)·I(-), the dihedral angle between the mean planes of the essentially planar furan (r.m.s. deviation = 0.007?Å) and phenyl rings is 48.4?(1)°. In the crystal, cations and anions are arranged in layers lying parallel to (100).

| S-EPMC3201454 | biostudies-literature

Isopropyl-triphenyl-phospho-nium bromide monohydrate.

Project description:In the title water-solvated salt, C(21)H(22)P(+)·Br(-)·H(2)O, the ionic components are linked by short C-H⋯Br contacts along the a-axis direction. The two half occupied water mol-ecules are connected to each other by strong O-H⋯O hydrogen bonds and they are also linked to the bromide anion by short O-H⋯Br contacts.

| S-EPMC3238822 | biostudies-literature

P-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl-thio-phosphinic amide.

Project description:The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra-hydro-furan. In the solid state, intra-molecular N-H⋯S hydrogen bonding influences the mol-ecular conformation; a P-N-P-N torsion angle of 2.28 (9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02 (4)°.

| S-EPMC2977763 | biostudies-literature

Ethyl [(benzyl-aza-nium-yl)(2-hy-droxy-phen-yl)meth-yl]phospho-nate.

Project description:The title compound, C(16)H(20)NO(4)P, crystallizes as a zwitterion. In the mol-ecule, the two aromatic rings form a dihedral angle of 55.2?(1)°. In the crystal, inter-molecular N-H?O and O-H?O hydrogen bonds link the mol-ecules into columns propagating in [010].

| S-EPMC3213461 | biostudies-literature

(4-Methoxy-benzoyl-meth-yl)triphenyl-phospho-nium trifluoro-methane-sulfonate.

Project description:Colourless crystals of the title compound, C(27)H(24)O(2)P(+)·CF(3)SO(3) (-), have been prepared by the addition of a solution of AgCF(3)SO(3) in methanol to a solution of (4-methoxy-benzoyl-meth-yl)triphenyl-phospho-nium bromide in dry methanol. There are two crystallographically independent mol-ecules in the asymmetric unit. The crystal structure is stabilized by inter- and intra-molecular C-H?O hydrogen bonds and further stabilized by C-H?? inter-actions.

| S-EPMC2968230 | biostudies-literature

[Amino-(iminio)meth-yl]phospho-nate.

Project description:The title compound, CH(5)N(2)O(3)P, exists as a zwitterion. The N atom of the imino group is protonated and the phospho-nic acid group is deprotonated. The mol-ecular geometry about the central C atom of this zwitterionic species was found to be strictly planar with the sum of the three angles about C being precisely 360°. In the crystal, the mol-ecules are inter-linked by O-H⋯O and N-H⋯O hydrogen-bonding inter-actions, forming a three-dimensional supra-molecular network structure.

| S-EPMC3007934 | biostudies-literature

Diisopropyl [(benzoyl-amino)-(phen-yl)meth-yl]phospho-nate.

Project description:The title compound, C(20)H(26)NO(4)P, has been obtained by the reaction of benzoyl chloride and diisoprop-yl[amino-(phen-yl)meth-yl]phospho-nate. The dihedral angle between the planes of the benzoyl-amino group and the phenyl ring is 77.0?(2)°. The crystal structure is stabilized by strong inter-molecular N-H?O hydrogen bonds between the doubly bonded phosphoryl O atom and the amide N atom which link the mol-ecules into pairs about a center of symmetry.

| S-EPMC2968692 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data