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(Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide.

ABSTRACT: The title compound, C(16)H(21)NP(+)·I(-), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P-N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98?(5)°. A weak donor-acceptor N-H?I inter-action is observed.

SUBMITTER: Peulecke N

PROVIDER: S-EPMC3151846 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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(Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide.

Peulecke Normen N Peitz Stephan S Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20110618 Pt 7

The title compound, C(16)H(21)NP(+)·I(-), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P-N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor-acceptor N-H⋯I inter-action is observed. ...[more]

PMID: 21837129

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