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Homopiperazine-1,4-diium bis-[hexa-aqua-cobalt(II)] tris-ulfate.

ABSTRACT: In the title compound, (C(5)H(14)N(2))[Co(H(2)O)(6)](2)(SO(4))(3), the cationic framework is built up of mixed organic-inorganic fragments, namely [Co(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+). The [Co(H(2)O)(6)](2+) cations form unconnected octa-hedra. Sulfate anions inter-calated between cationic species connect them via N-H?O and O-H?O hydrogen bonds and electrostatic inter-actions.

SUBMITTER: Sahbani T

PROVIDER: S-EPMC3212155 | biostudies-other | 2011 Aug

REPOSITORIES: biostudies-other

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Homopiperazine-1,4-diium bis-[hexa-aqua-cobalt(II)] tris-ulfate.

Sahbani Thameur T Smirani Sta Wajda W S Al-Deyab Salem S Rzaigui Mohamed M

Acta crystallographica. Section E, Structure reports online 20110713 Pt 8

In the title compound, (C(5)H(14)N(2))[Co(H(2)O)(6)](2)(SO(4))(3), the cationic framework is built up of mixed organic-inorganic fragments, namely [Co(H(2)O)(6)](2+) and [C(5)H(14)N(2)](2+). The [Co(H(2)O)(6)](2+) cations form unconnected octa-hedra. Sulfate anions inter-calated between cationic species connect them via N-H⋯O and O-H⋯O hydrogen bonds and electrostatic inter-actions. ...[more]

PMID: 22090857

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