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Aqua-[tris-(2-{5-[(4-methyl-phenyl)diazen-yl]-2-oxidobenzyl-idene-amino}-eth-yl)amine]-samarium(III) acetonitrile monosolvate.

ABSTRACT: In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta-dentate tris-(2-{5-[(4-methyl-pheny)diazen-yl]-2-oxidobenzyl-idene-amino}-eth-yl)amine trianionic ligand and a water mol-ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square anti-prism. In the crystal, complex mol-ecules are linked by O-H?O hydrogen bonds.

SUBMITTER: Salehzadeh S

PROVIDER: S-EPMC3274845 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Aqua-[tris-(2-{5-[(4-methyl-phenyl)diazen-yl]-2-oxidobenzyl-idene-amino}-eth-yl)amine]-samarium(III) acetonitrile monosolvate.

Salehzadeh Sadegh S Mahdavian Mahsa M Khalaj Mehdi M

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta-dentate tris-(2-{5-[(4-methyl-pheny)diazen-yl]-2-oxidobenzyl-idene-amino}-eth-yl)amine trianionic ligand and a water mol-ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square anti-prism. In the crystal, complex mol-ecules are linked by O-H⋯O hydrogen bonds. ...[more]

PMID: 22346894

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