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Bis[N-(3-amino-prop-yl)propane-1,3-di-amine-?N,N',N'']cadmium nitrate perchlorate.

ABSTRACT: The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis-(3-amino-prop-yl)-amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis-(3-amino-prop-yl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis-(3-amino-prop-yl)amine ligands in a slightly distorted octa-hedral coordination geometry. In the crystal, mol-ecules are held together by an intricate network of N-H?O inter-actions. One of the two amine ligands was found to be disordered over two sets of sites, with a ratio of 0.802?(3):0.198?(3), similarly to the nitrate anion, with a ratio of 0.762?(10):0.238?(10).

SUBMITTER: Goudarziafshar H

PROVIDER: S-EPMC3297233 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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Bis[N-(3-amino-prop-yl)propane-1,3-di-amine-κN,N',N'']cadmium nitrate perchlorate.

Goudarziafshar Hamid H Nikoorazm Mohsen M Abbasityula Yunes Y Eigner Václav V Dušek Michal M

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

The title complex, [Cd(C(6)H(17)N(3))(2)](ClO(4))(NO(3)), was synthesized by the reaction of Cd(NO(3))(2)·4H(2)O, bis-(3-amino-prop-yl)-amine and sodium perchlorate in methanol. The asymmetric unit of the title complex consists of one Cd(2+) cation, two tridentate bis-(3-amino-prop-yl)amine ligands, one nitrate anion and one perchlorate anion. The Cd(2+) cation is coordinated by six N atoms of the bis-(3-amino-prop-yl)amine ligands in a slightly distorted octa-hedral coordination geometry. In th ...[more]

PMID: 22412423

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