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Trans-Tetra-kis[N-(adamantan-1-yl)pyridine-4-carboxamide]-dichlorido-manganese(II)-N-(adamantan-1-yl)pyridine-4-carboxamide (1/2).

ABSTRACT: The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecules, one Cl(-) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecule. The distorted octa-hedral Mn environment comprises two terminal Cl atoms and four monodentate N atoms from four organic ligands. All the carbamoyl N atoms are involved in inter-molecular N-H?O hydrogen-bonding inter-actions which link the mol-ecules into a chain along the a axis.

SUBMITTER: Wang YC

PROVIDER: S-EPMC3343817 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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trans-Tetra-kis[N-(adamantan-1-yl)pyridine-4-carboxamide]-dichlorido-manganese(II)-N-(adamantan-1-yl)pyridine-4-carboxamide (1/2).

Wang Ying-Chun YC

Acta crystallographica. Section E, Structure reports online 20120314 Pt 4

The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecules, one Cl(-) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecule. The distorted octa-hedral Mn environment comprises two terminal Cl atoms and four monodentate N atoms from four organic ligands. All the carbamoyl N atoms are involved in inter-molecular N-H⋯O hydr ...[more]

PMID: 22589791

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