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Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato-?(2)O(1),N,N',O(1')}cobalt(III) dimethyl-formamide monosolvate.

ABSTRACT: In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetra-dentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethyl-formamide (DMF) monosolvate. In the crystal, complex mol-ecules are linked via O-H(water)?O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C-H?Cl inter-action, and the DMF mol-ecule is linked to the complex mol-ecule by C-H?O inter-actions.

SUBMITTER: Wei Y

PROVIDER: S-EPMC3343852 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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Aqua-chlorido{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato-κ(2)O(1),N,N',O(1')}cobalt(III) dimethyl-formamide monosolvate.

Wei Yun Y Pang Ting T Liu Jiacheng J Li Meng M Liang Lili L

Acta crystallographica. Section E, Structure reports online 20120321 Pt 4

In the title compound, [Co(C(18)H(18)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Co(III) ion is six-coordinated by a tetra-dentate 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethyl-formamide (DMF) monosolvate. In the crystal, complex mol-ecules are linked via O-H(water)⋯O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C-H⋯Cl inter-ac ...[more]

PMID: 22589826

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