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Tetra-kis(nitrato-?(2)O,O')[N,N'-1,4-phenyl-enebis(pyridine-4-carboxamide)-?N(1)](4-{[4-(pyridine-4-carboxamido-?N(1))phen-yl]carbamo-yl}pyridin-1-ium)neodymium(III).

ABSTRACT: In the title compound, [Nd(NO(3))(4)(C(18)H(15)N(4)O(2))(C(18)H(14)N(4)O(2))], the Nd(III) centre is located on a twofold axis and exhibits a ten-coordinated distorted bicapped square-anti-prismatic geometry. The pyridinium NH H atom is disordered over the two ligands. Adjacent mononuclear clusters are linked through N-H?O and N-H?N hydrogen-bonding inter-actions, generating layers in the (102) plane.

SUBMITTER: Zhang Y

PROVIDER: S-EPMC3343854 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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Tetra-kis(nitrato-κ(2)O,O')[N,N'-1,4-phenyl-enebis(pyridine-4-carboxamide)-κN(1)](4-{[4-(pyridine-4-carboxamido-κN(1))phen-yl]carbamo-yl}pyridin-1-ium)neodymium(III).

Zhang Yun Y Hao Jiao-Jiao JJ Zhou Hu H

Acta crystallographica. Section E, Structure reports online 20120321 Pt 4

In the title compound, [Nd(NO(3))(4)(C(18)H(15)N(4)O(2))(C(18)H(14)N(4)O(2))], the Nd(III) centre is located on a twofold axis and exhibits a ten-coordinated distorted bicapped square-anti-prismatic geometry. The pyridinium NH H atom is disordered over the two ligands. Adjacent mononuclear clusters are linked through N-H⋯O and N-H⋯N hydrogen-bonding inter-actions, generating layers in the (102) plane. ...[more]

PMID: 22589828

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