Unknown

Dataset Information

0

2-(1,3-Dioxoisoindolin-2-yl)acetic acid-N'-[(E)-4-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide (2/1).

ABSTRACT: In the crystal structure of the title compound, 2C(10)H(7)NO(4)·C(14)H(13)N(3)O(2), the two independent acid mol-ecules are connected through strong O-H?N and O-H?O hydrogen bonds to the central mol-ecule of the anti-tubercular drug N'-[(E)-4-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide. Two such trimolecular units related by an inversion centre inter-act through a pair of N-H?O hydrogen bonds, forming a 3 + 3 mol-ecular aggregate. The dihedral angle between the aromatic rings of the hydrazone mol-ecule is 1.99?(12)°. The crystal packing features weak C-H?O and ?-? stacking inter-actions, with centroid-centroid distances of 3.8460?(19) and 3.8703?(13)?Å.

SUBMITTER: Novakovic SB 

PROVIDER: S-EPMC3470249 | biostudies-other | 2012 Oct

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

2-(1,3-Dioxoisoindolin-2-yl)acetic acid-N'-[(E)-4-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide (2/1).

Novaković Sladjana B SB   Bogdanović Goran A GA   Mohamed Shaaban K SK   Albayati Mustafa R MR   Hameed Ayad S AS  

Acta crystallographica. Section E, Structure reports online 20120908 Pt 10

In the crystal structure of the title compound, 2C(10)H(7)NO(4)·C(14)H(13)N(3)O(2), the two independent acid mol-ecules are connected through strong O-H⋯N and O-H⋯O hydrogen bonds to the central mol-ecule of the anti-tubercular drug N'-[(E)-4-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide. Two such trimolecular units related by an inversion centre inter-act through a pair of N-H⋯O hydrogen bonds, forming a 3 + 3 mol-ecular aggregate. The dihedral angle between the aromatic rings of the hydrazon  ...[more]

Similar Datasets

Unknown 2-(1,3-Dioxoisoindolin-2-yl)acetic acid-N'-[(E)-2-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide (1/1).
| S-EPMC3414356 | biostudies-literature
Unknown (E)-N'-(4-Meth-oxy-benzyl-idene)pyridine-3-carbohydrazide dihydrate.
| S-EPMC3770434 | biostudies-literature
Unknown N'-[(E)-2-Hy-droxy-5-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide.
| S-EPMC3009050 | biostudies-literature
Unknown N'-[(E)-2-Hy-droxy-5-meth-oxy-benzyl-idene]pyridine-4-carbohydrazide monohydrate.
| S-EPMC3685038 | biostudies-literature
Unknown N'-[(E)-2-Meth-oxy-benzyl-idene]pyrazine-2-carbohydrazide.
| S-EPMC3152029 | biostudies-literature
Unknown (E)-N'-[3-(4-Chloro-benzo-yloxy)benzyl-idene]pyridine-4-carbohydrazide acetic acid monosolvate monohydrate.
| S-EPMC3344622 | biostudies-literature
Unknown 2-(2-{[2-(4-Pyridylcarbon-yl)hydrazinyl-idene]meth-yl}phen-oxy)acetic acid.
| S-EPMC2979532 | biostudies-literature
Unknown 2-{2-[(E)-(2-Benzoyl-hydrazin-1-yl-idene)meth-yl]phen-oxy}acetic acid.
| S-EPMC3394044 | biostudies-literature
Unknown 2-{[2-(2-Hy-droxy-3-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-6-meth-oxy-phenol.
| S-EPMC3201493 | biostudies-literature
Unknown 2-{[2-(2-Hy-droxy-5-meth-oxy-benzyl-idene)hydrazin-1-yl-idene]meth-yl}-4-meth-oxy-phenol.
| S-EPMC3998297 | biostudies-literature