(6bS*,14R*,14aR*)-Methyl 14-(4-methyl-phen-yl)-7-oxo-6b,6c,7,12b,14,14a-hexa-hydro-1H-pyrano[3,2-c:5,4-c']dichromene-14a-carboxyl-ate.

ABSTRACT: In the title compound, C(28)H(22)O(6), the chromeno ring system is almost planar, with a dihedral angle between the mean planes of the pyran and benzene rings of 1.87?(8)°. The pyran ring bearing the methyl-phenyl substituent has a half-chair conformation while the other pyran ring has an envelope conformation with the tetra-substituted C atom as the flap. The benzene ring of the chromeno ring system is inclined to the benzene ring fused to the latter pyran ring by 74.66?(9)°. These aromatic rings are inclined to the 4-methyl-phenyl ring by 52.67?(9) and 66.63?(10)°, respectively. In the crystal, mol-ecules are linked via C-H?O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.

SUBMITTER: Ponnusamy R 

PROVIDER: S-EPMC3569797 | biostudies-other | 2013 Feb

REPOSITORIES: biostudies-other