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Bis(2,2',2''-nitrilo-triacetamide-?(3) O,N,O')cobalt(II) dinitrate tetra-hydrate.


ABSTRACT: In the centrosymmetric title compound, [Co(C6H12N4O3)2](NO3)2·4H2O, the Co(II) ion, lying on an inversion center, is O,N,O'-chelated by two nitrilo-triacetamide mol-ecules, forming a distorted octa-hedral geometry. In the crystal, extensive O-H?O and N-H?O hydrogen bonds link the complex cations, nitrate anions and lattice water mol-ecules into a three-dimensional network.

SUBMITTER: Ran JW 

PROVIDER: S-EPMC3684886 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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Bis(2,2',2''-nitrilo-triacetamide-κ(3) O,N,O')cobalt(II) dinitrate tetra-hydrate.

Ran Jing-Wen JW   Pei Jun J  

Acta crystallographica. Section E, Structure reports online 20130518 Pt 6


In the centrosymmetric title compound, [Co(C6H12N4O3)2](NO3)2·4H2O, the Co(II) ion, lying on an inversion center, is O,N,O'-chelated by two nitrilo-triacetamide mol-ecules, forming a distorted octa-hedral geometry. In the crystal, extensive O-H⋯O and N-H⋯O hydrogen bonds link the complex cations, nitrate anions and lattice water mol-ecules into a three-dimensional network. ...[more]

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