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Catena-Poly[[(tri-phenyl-phosphane-?P)silver(I)]-?-4,4'-bi-pyridine-?(2) N:N'-[(tri-phenyl-phosphane-?P)silver(I)]-di-?-chlorido].

ABSTRACT: In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2] n , the Ag(I) cation is coordinated by a 4,4'-bi-pyridine N atom, a tri-phenyl-phosphane P atom and two Cl(-) anions in a distorted tetra-hedral geometry. The 4,4-bi-pyridine and Cl(-) anions bridge the Ag(I) cations, forming polymeric chains running along [21-1]. In the crystal, weak C-H?Cl inter-actions link the polymeric chains into a three-dimensiona supra-molecular architecture.

SUBMITTER: Song XM

PROVIDER: S-EPMC3684900 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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catena-Poly[[(tri-phenyl-phosphane-κP)silver(I)]-μ-4,4'-bi-pyridine-κ(2) N:N'-[(tri-phenyl-phosphane-κP)silver(I)]-di-μ-chlorido].

Song Xiao-Ming XM Hu Feng F Shi Hua-Tian HT Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20130525 Pt 6

In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2] n , the Ag(I) cation is coordinated by a 4,4'-bi-pyridine N atom, a tri-phenyl-phosphane P atom and two Cl(-) anions in a distorted tetra-hedral geometry. The 4,4-bi-pyridine and Cl(-) anions bridge the Ag(I) cations, forming polymeric chains running along [21-1]. In the crystal, weak C-H⋯Cl inter-actions link the polymeric chains into a three-dimensiona supra-molecular architecture. ...[more]

PMID: 23795002

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