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Chlorido-{2-[(di-methyl-amino)-meth-yl]benzene-seleno-lato-?(2) N,Se}(tri-phenyl-phosphane-?P)palladium(II).

ABSTRACT: The asymmetric unit of the title compound, [PdCl(C9H12NSe)(C18H15P)], contains two independent mol-ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di-methyl-amino)-meth-yl]benzene-seleno-late ligand. The chloride ligand lies trans to selenium and the tri-phenyl-phosphane ligand is trans to nitro-gen. The Pd-Se bond lengths in the two independent coordination environments of Pd are 2.3801?(4) and 2.3852?(4)?Å, the Pd-P bond lengths are 2.2562?(8) and 2.2471?(8)?Å, the Pd-N bond lengths are 2.172?(2) and 2.158?(2)?Å, and the Pd-Cl bond lengths are 2.3816?(8) and 2.3801?(8)?Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other.

SUBMITTER: Takaluoma EM

PROVIDER: S-EPMC4051070 | biostudies-literature | 2014 Jun

REPOSITORIES: biostudies-literature

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Chlorido-{2-[(di-methyl-amino)-meth-yl]benzene-seleno-lato-κ(2) N,Se}(tri-phenyl-phosphane-κP)palladium(II).

Takaluoma Esther M EM Oilunkaniemi Raija R Laitinen Risto S RS

Acta crystallographica. Section E, Structure reports online 20140517 Pt 6

The asymmetric unit of the title compound, [PdCl(C9H12NSe)(C18H15P)], contains two independent mol-ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di-methyl-amino)-meth-yl]benzene-seleno-late ligand. The chloride ligand lies trans to selenium and the tri-phenyl-phosphane ligand is trans to nitro-gen. The Pd-Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd-P bond lengths ar ...[more]

PMID: 24940202

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