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Bis[1-meth-oxy-2,2,2-tris-(pyrazol-1-yl-?N (2))ethane]-nickel(II) bis-(tri-fluoro-methane-sulfonate) methanol disolvate.

ABSTRACT: In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2CH3OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth-oxy-2,2,2-tris-(pyrazol-1-yl)ethane ligands in a distorted octa-hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni-N distances range from 2.0589?(19) to 2.0757?(19)?Å, intra-ligand N-Ni-N angles range from 84.50?(8) to 85.15?(8)°, and adjacent inter-ligand N-Ni-N angles range between 94.85?(8) and 95.50?(8)°. In the crystal, O-H?O hydrogen bonds between methanol solvent mol-ecules and tri-fluoro-methane-sulfonate anions are observed.

SUBMITTER: Lyubartseva G

PROVIDER: S-EPMC3790348 | biostudies-other | 2013

REPOSITORIES: biostudies-other

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Bis[1-meth-oxy-2,2,2-tris-(pyrazol-1-yl-κN (2))ethane]-nickel(II) bis-(tri-fluoro-methane-sulfonate) methanol disolvate.

Lyubartseva Ganna G Parkin Sean S Mallik Uma Prasad UP

Acta crystallographica. Section E, Structure reports online 20130912 Pt 10

In the title salt, [Ni(C12H14N6O)2](CF3SO3)2·2CH3OH, the Ni(II) ion is coordinated by six N atoms from two tridentate 1-meth-oxy-2,2,2-tris-(pyrazol-1-yl)ethane ligands in a distorted octa-hedral geometry. The Ni(II) ion is situated on an inversion centre. The Ni-N distances range from 2.0589 (19) to 2.0757 (19) Å, intra-ligand N-Ni-N angles range from 84.50 (8) to 85.15 (8)°, and adjacent inter-ligand N-Ni-N angles range between 94.85 (8) and 95.50 (8)°. In the crystal, O-H⋯O hydrogen bonds bet ...[more]

PMID: 24098170

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Bis[1-meth-oxy-2,2,2-tris-(pyrazol-1-yl-?N (2))ethane]-nickel(II) bis-(tri-fluoro-methane-sulfonate) dihydrate.

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