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5,6-Dimeth-yl-1,10-phenanthroline.

ABSTRACT: In the title compound, C14H12N2, the N?N distance is 2.719?(1)?Å. The N-C-C-N torsion angle [0.9?(1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimeth-yl[1,10]phenanthroline. In the crystal, C-H?N hydrogen bonds link the mol-ecules into C(4) chains running parallel to the b axis. Weak ?-? inter-actions between benzene and pyridine rings [centroid-centroid distance = 3.5337?(7)?Å] and between benzene rings [centroid-centroid distances = 3.6627?(7) and 3.8391?(7)Å] also occur.

SUBMITTER: Rozenel SS

PROVIDER: S-EPMC3790421 | biostudies-other | 2013

REPOSITORIES: biostudies-other

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5,6-Dimeth-yl-1,10-phenanthroline.

Rozenel Sergio S SS

Acta crystallographica. Section E, Structure reports online 20130918 Pt 10

In the title compound, C14H12N2, the N⋯N distance is 2.719 (1) Å. The N-C-C-N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimeth-yl[1,10]phenanthroline. In the crystal, C-H⋯N hydrogen bonds link the mol-ecules into C(4) chains running parallel to the b axis. Weak π-π inter-actions between benzene and pyridine rings [centroid-centroid distance = 3.5337 (7) Å] and bet ...[more]

PMID: 24098240

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