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Crystal structure of methyl (2Z)-3-(4-chloro-phen-yl)-2-[(3-methyl-1H-indol-1-yl)meth-yl]prop-2-enoate.

ABSTRACT: In the title indole derivative, C20H18ClNO2, the chloro-phenyl ring is almost perpendicular to the indole moiety, making a dihedral angle of 87.6?(1)°. The mol-ecular packing is stabilized by C-H?? inter-actions, which form a C(9) chain motif along [10-1]. In addition, there are weak ?-? inter-actions [centroid-centroid distance 3.851?(1)?Å] between the chains, involving inversion-related chloro-phenyl rings.

SUBMITTER: Selvanayagam S

PROVIDER: S-EPMC4459359 | biostudies-other | 2015 Jun

REPOSITORIES: biostudies-other

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Crystal structure of methyl (2Z)-3-(4-chloro-phen-yl)-2-[(3-methyl-1H-indol-1-yl)meth-yl]prop-2-enoate.

Selvanayagam S S Sridhar B B Kathiravan S S Raghunathan R R

Acta crystallographica. Section E, Crystallographic communications 20150530 Pt 6

In the title indole derivative, C20H18ClNO2, the chloro-phenyl ring is almost perpendicular to the indole moiety, making a dihedral angle of 87.6 (1)°. The mol-ecular packing is stabilized by C-H⋯π inter-actions, which form a C(9) chain motif along [10-1]. In addition, there are weak π-π inter-actions [centroid-centroid distance 3.851 (1) Å] between the chains, involving inversion-related chloro-phenyl rings. ...[more]

PMID: 26090160

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