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An in-situ synthesis of Ag/AgCl/TiO2/hierarchical porous magnesian material and its photocatalytic performance.

ABSTRACT: The absorption ability and photocatalytic activity of photocatalytic materials play important roles in improving the pollutants removal effects. Herein, we reported a new kind of photocatalytic material, which was synthesized by simultaneously designing hierarchical porous magnesian (PM) substrate and TiO2 catalyst modification. Particularly, PM substrate could be facilely prepared by controlling its crystal phase (Phase 5, Mg3Cl(OH)5 · 4H2O), while Ag/AgCl particles modification of TiO2 could be achieved by in situ ion exchange between Ag(+) and above crystal Phase. Physiochemical analysis shows that Ag/AgCl/TiO2/PM material has higher visible and ultraviolet light absorption response, and excellent gas absorption performance compared to other controls. These suggested that Ag/AgCl/TiO2/PM material could produce more efficient photocatalytic effects. Its photocatalytic reaction rate was 5.21 and 30.57 times higher than that of TiO2/PM and TiO2/imporous magnesian substrate, respectively. Thus, this material and its intergration synthesis method could provide a novel strategy for high-efficiency application and modification of TiO2 photocatalyst in engineering filed.

SUBMITTER: Yang L

PROVIDER: S-EPMC4756697 | biostudies-other | 2016

REPOSITORIES: biostudies-other

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Photogenerated Oxygen Vacancies in Hierarchical Ag/TiO2 Nanoflowers for Enhanced Photocatalytic Reactions.

Project description:Oxygen vacancy (Vo) creation and morphology controlling make significant contributions to the electronic and structural regulation of metal oxide semiconductors, yet an investigation about convenient approaches for fabricating hierarchical catalyst with abundant oxygen vacancies still has significant challenges. Here, we report a unique method to create abundant oxygen vacancies in hierarchical Ag/TiO2 nanoflowers during photocatalytic reaction, which is accompanied by light absorption variation and surface plasmon resonance (SPR) enhancement. Its high efficiency of photocatalytic H2 evolution (the highest apparent quantum yield reaches 3.2% at 365 nm) and rhodamine B degradation can be considered as benefits from the synergistic effects of the well-arranged hierarchical structure, the photogenerated oxygen vacancies, and the SPR of cocatalyst Ag. This work proposes an effective strategy to optimize the synthesis of regular hierarchical structures and enriches the research on the vital function of oxygen vacancies in photocatalytic reactions.

| S-EPMC7301581 | biostudies-literature

Correction: Photocatalytic antibacterial performance of TiO2 and Ag-doped TiO2 against S. aureus. P. aeruginosa and E. coli.

Project description:[This corrects the article DOI: 10.3762/bjnano.4.40.].

| S-EPMC7136558 | biostudies-literature

Hierarchical Nanotube-Constructed Porous TiO2-B Spheres for High Performance Lithium Ion Batteries.

Project description:Hierarchically structured porous TiO2-B spheres have been synthesized via a hydrothermal process using amorphous titania/oleylamine composites as a self-sacrificing template. The TiO2-B spheres are constructed by interconnected nanotubes and possess a high specific surface area of 295 m(2) g(-1). When evaluated as an anode material in lithium-half cells, the as-obtained TiO2-B material exhibits high and reversible lithium storage capacity of 270 mA h g(-1) at 1 C (340 mA g(-1)), excellent rate capability of 221 mA h g(-1) at 10 C, and long cycle life with over 70% capacity retention after 1000 cycles at 10 C. The superior electrochemical performance of TiO2-B material strongly correlates to the synergetic superiorities with a combination of TiO2-B polymorph, hierarchically porous structure, interconnected nanotubes and spherical morphology. Post-mortem structural analyses reveal some discrete cubic LiTiO2 nanodots formed on the outer surfaces of TiO2-B nanotubes, which might account for the slight capacity loss upon prolonged electrochemical cycling.

| S-EPMC4501008 | biostudies-literature

One-Step Synthesis of Ag@TiO? Nanoparticles for Enhanced Photocatalytic Performance.

Project description:Polyamide network polymers (PNP) modified TiO? nanoparticles (NPs) were decorated with Ag NPs in hydrothermal gel method, forming one-step synthesized photocatalysts, Ag@TiO? NPs. The effect of PNP and the amount of Ag NPs added were investigated in this work. PNP acted as a nanocage to prevent TiO? aggregation and capture Ag accurately, which could effectively control product sizes and improve dispersibility in solvents. Simultaneously, TiO? NPs modified with Ag NPs exhibited remarkable photocatalytic effects. One-step synthesis simplified the experimental process and avoided the agglomeration of silver ions during the secondary reaction, achieving the purpose of uniform distribution at a specific location of TiO? NPs. The prepared Ag@TiO? NPs-0.5 could remove 79.49% of Methyl Orange (MO) after 3 h of ultraviolet light irradiation, which was 2.7 times higher than the reaction rate of pure TiO? NPs. It also exhibited good photoactivity under Visible light conditions. Moreover, the mineralization rate of MO over the Ag@TiO2 NPs-0.5 could be up to 72.32% under UV light and 47.08% under Visible light irradiation, which revealed that the prepared catalysts could effectively degrade most of the MO to CO? and H?O. The samples also demonstrated the excellent stability and easy recyclability with over 90% of the original catalytic level for MO degradation. The photocatalysts studied also exerted broad application prospects such as photovoltaic hydrogen production, electronic sensors and biomedicine.

| S-EPMC6316728 | biostudies-literature

Microwave-Assisted Synthesis of High-Energy Faceted TiO2 Nanocrystals Derived from Exfoliated Porous Metatitanic Acid Nanosheets with Improved Photocatalytic and Photovoltaic Performance.

Project description:A facile one-pot microwave-assisted hydrothermal synthesis of rutile TiO2 quadrangular prisms with dominant {110} facets, anatase TiO2 nanorods and square nanoprisms with co-exposed {101}/[111] facets, anatase TiO2 nanorhombuses with co-exposed {101}/{010} facets, and anatase TiO2 nanospindles with dominant {010} facets were reported through the use of exfoliated porous metatitanic acid nanosheets as a precursor. The nanostructures and the formation reaction mechanism of the obtained rutile and anatase TiO2 nanocrystals from the delaminated nanosheets were investigated. The transformation from the exfoliated metatitanic nanosheets with distorted hexagonal cavities to TiO2 nanocrystals involved a dissolution reaction of the nanosheets, nucleation of the primary [TiO6]8- monomers, and the growth of rutile-type and anatase-type TiO2 nuclei during the microwave-assisted hydrothermal reaction. In addition, the photocatalytic activities of the as-prepared anatase nanocrystals were evaluated through the photocatalytic degradation of typical carcinogenic and mutagenic methyl orange (MO) under UV-light irradiation at a normal temperature and pressure. Furthermore, the dye-sensitized solar cell (DSSC) performance of the synthesized anatase TiO2 nanocrystals with various morphologies and crystal facets was also characterized. The {101}/[111]-faceted pH2.5-T175 nanocrystal showed the highest photocatalytic and photovoltaic performance compared to the other TiO2 samples, which could be attributed mainly to its minimum particle size and maximum specific surface area.

| S-EPMC6862389 | biostudies-literature

Preparation of pod-shaped TiO2 and Ag@TiO2 nano burst tubes and their photocatalytic activity.

Project description:The pod-shaped TiO2 nano burst tubes (TiO2 NBTs) were prepared by the combination of electrospinning and impregnation calcination with oxalic acid (H2C2O4), polystyrene (PS) and tetrabutyl titanate. The silver nanoparticles (AgNPs) were loaded onto the surface of TiO2 NBTs by ultraviolet light reduction method to prepare pod-shaped Ag@TiO2 NBTs. In this work, we analysed the effect of the amount of oxalic acid on the cracking degree of TiO2 NBTs; the effect of the concentration of AgNO3 solution on the particle size and loading of AgNPs on the surface of TiO2 NBTs. Scanning electron microscopy and transmission electron microscopy investigated the surface morphology of samples. X-ray diffraction and X-ray photoelectron spectroscopy characterized the structure and composition of samples. Rhodamine B (RhB) solution was used to evaluate the photocatalytic activity of pod-shaped TiO2 NBTs and Ag@TiO2 NBTs. The results showed that TiO2 NBTs degraded 91.0% of RhB under ultraviolet light, Ag@TiO2 NBTs degraded 95.5% under visible light for 75 and 60 min, respectively. The degradation process of both samples was consistent with the Langmuir-Hinshelwood first-order kinetic equation. Therefore, the catalytic performance of the sample is: Ag@TiO2 NBTs > TiO2 NBTs > TiO2 nanotubes.

| S-EPMC6774943 | biostudies-literature

Plasmonic enhanced photocatalytic activity of Ag/TiO2 tube-in-tube fibers.

Project description:Ag nanoparticle was found to significantly enhance the photocatalytic activity of self-organized TiO2 nanotube structures. Herein, novel Ag/TiO2 tube-in-tube fibers have been prepared by a facile electrospinning technology and calcination process. Employed as the photocatalyst, the composite could efficiently catalyze the photodegradation of the model organic pollutant, rhodamine B under visible light irradiation, exhibiting a superior photocatalytic activity than the undoped TiO2 tube-in-tube fibers. This enhanced activity has been ascribed to plasmonic characteristics of Ag nanoparticles, which promote the light absorption and charge transfer feasibility. The simple, low-cost and green fabrication route of the composite provides a novel means for preparing similar materials, holding great promise for wider application in the future.

| S-EPMC9752503 | biostudies-literature

One-step synthesis of OH-TiO2/TiOF2 nanohybrids and their enhanced solar light photocatalytic performance.

Project description:TiO2/TiOF2 nanohybrids were quickly synthesized through a hydrothermal process using titanium n-butoxide (TBOT), ethanol (C2H5OH) and hydrofluoric acid as precursors. The prepared nanohybrids underwent additional NaOH treatment (OH-TiO2/TiOF2) to enhance their photocatalytic performance. In this paper, the mechanism of NaOH affecting the pathway of transformation from TBOT (Ti precursor) to TiO2 nanosheets was discussed. The synthesized TiO2/TiOF2 and OH-TiO2/TiOF2 were characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction pattern (XRD), Fourier infrared spectroscopic analysis (FT-IR), Photoluminescence (PL) emission spectra and UV-visible diffuse reflection spectra (UV-vis DRS). The photocatalytic activity and stability of synthesized samples were evaluated by degradation of methylene blue (MB) under the simulated solar light. The results showed that a larger ratio of TiO2 to TiOF2 in TiO2/TiOF2 and OH-TiO2/TiOF2 nanohybrids could allow for even higher MB conversion compared with only TiO2 nanosheets. NaOH treatment can wash off the F ions from TiOF2 and induce this larger ratio. The highest efficiency of MB removal was just above 90% in 1 h. Lower electron-hole pairs recombination rate is the dominant factor that induces the photocatalytic performance enhancement of TiO2/TiOF2 nanohybrids. The synthesized OH-TiO2/TiOF2 nanohybrids exhibit great potential in the abatement of organic pollutants.

| S-EPMC6030343 | biostudies-literature

Facile synthesis of silver/silver thiocyanate (Ag@AgSCN) plasmonic nanostructures with enhanced photocatalytic performance.

Project description:A nanostructured plasmonic photocatalyst, silver/silver thiocyanate (Ag@AgSCN), has been prepared by a simple precipitation method followed by UV-light-induced reduction. The ratio of Ag to silver thiocyanate (AgSCN) can be controlled by simply adjusting the photo-induced reduction time. The formation mechanism of the product was investigated based on the time-dependent experiments. Further experiments indicated that the prepared Ag@AgSCN nanostructures with an atomic ratio of Ag/AgSCN = 0.0463 exhibited high photocatalytic activity and long-term stability for the degradation of oxytetracycline (84%) under visible-light irradiation. In addition to the microstructure and high specific surface area, the enhanced photocatalytic activity was mainly caused by the surface plasmon resonance of Ag nanoparticles, and the high stability of AgSCN resulted in the long-term stability of the photocatalyst product.

| S-EPMC5753043 | biostudies-literature

Effect of Multiply Twinned Ag(0) Nanoparticles on Photocatalytic Properties of TiO2 Nanosheets and TiO2 Nanostructured Thin Films.

Project description:Ag-decorated TiO2 nanostructured materials are promising photocatalysts. We used non-standard cryo-lyophilization and ArF laser ablation methods to produce TiO2 nanosheets and TiO2 nanostructured thin films decorated with Ag nanoparticles. Both methods have a common advantage in that they provide a single multiply twinned Ag(0) characterized by {111} twin boundaries. Advanced microscopy techniques and electron diffraction patterns revealed the formation of multiply twinned Ag(0) structures at elevated temperatures (500 °C and 800 °C). The photocatalytic activity was demonstrated by the efficient degradation of 4-chlorophenol and Total Organic Carbon removal using Ag-TiO2 nanosheets, because the multiply twinned Ag(0) served as an immobilized photocatalytically active center. Ag-TiO2 nanostructured thin films decorated with multiply twinned Ag(0) achieved improved photoelectrochemical water splitting due to the additional induction of a plasmonic effect. The photocatalytic properties of TiO2 nanosheets and TiO2 nanostructured thin films were correlated with the presence of defect-twinned structures formed from Ag(0) nanoparticles with a narrow size distribution, tuned to between 10 and 20 nm. This work opens up new possibilities for understanding the defects generated in Ag-TiO2 nanostructured materials and paves the way for connecting their morphology with their photocatalytic activity.

| S-EPMC8911912 | biostudies-literature

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