Ontology highlight
ABSTRACT:
SUBMITTER: Ajenjo J
PROVIDER: S-EPMC4778532 | biostudies-other | 2016
REPOSITORIES: biostudies-other
Beilstein journal of organic chemistry 20160203
3-Fluoro-5-nitro-1-(pentafluorosulfanyl)benzene was prepared by three different ways: as a byproduct of direct fluorination of 1,2-bis(3-nitrophenyl)disulfane, by direct fluorination of 4-nitro-1-(pentafluorosulfanyl)benzene, and by fluorodenitration of 3,5-dinitro-1-(pentafluorosulfanyl)benzene. The title compound was subjected to a nucleophilic aromatic substitution of the fluorine atom with oxygen, sulfur and nitrogen nucleophiles affording novel (pentafluorosulfanyl)benzenes with 3,5-disubst ...[more]