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Crystal structure of 1,2-bis-((benzyl-sulfan-yl){2-[1-(2-hy-droxy-phen-yl)ethyl-idene]hydrazin-1-yl-idene}meth-yl)disulfane.

ABSTRACT: The title compound, C32H30N4O2S4, consists of two Schiff base moieties, namely two S-benzyl-?-N-(2-hy-droxy-phenyl-ethyl-idene)di-thio-carbazate groups, which are connected through an S-S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88?(4)° between the S2C=N planes. A bifurcated intra-molecular O-H?(N,S) hydrogen bond is observed in each moiety. In the crystal, mol-ecules are linked by pairs of C-H?O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C-H?? inter-actions.

SUBMITTER: Islam MA

PROVIDER: S-EPMC4778811 | biostudies-other | 2016 Mar

REPOSITORIES: biostudies-other

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Crystal structure of 1,2-bis-((benzyl-sulfan-yl){2-[1-(2-hy-droxy-phen-yl)ethyl-idene]hydrazin-1-yl-idene}meth-yl)disulfane.

Islam M A A A A MA Sheikh M C MC Islam M H MH Miyatake R R Zangrando E E

Acta crystallographica. Section E, Crystallographic communications 20160217 Pt 3

The title compound, C32H30N4O2S4, consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hy-droxy-phenyl-ethyl-idene)di-thio-carbazate groups, which are connected through an S-S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88 (4)° between the S2C=N planes. A bifurcated intra-molecular O-H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, mol-ecules are linked by pairs of C-H⋯O hydrogen bonds into inversion dimers. The ...[more]

PMID: 27006802

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