Ontology highlight
ABSTRACT:
SUBMITTER: Triantis C
PROVIDER: S-EPMC4778812 | biostudies-other | 2016 Mar
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Crystallographic communications 20160217 Pt 3
In the title compound, [Re(C10H6NO2)(C7H11N)(CO)3], the Re(I) atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C4NO coordination sphere is distorted octa-hedral. A lengthening of the axial Re-CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced π-π int ...[more]