Unknown

Dataset Information

0

Crystal structure of bis-(2-methyl-1H-imidazol-3-ium) di-hydroxidobis(oxalato-?(2) O (1),O (2))stannate(IV) monohydrate.

ABSTRACT: In the structure of the hydrated title salt, (C4H7N2)2[Sn(C2O4)2(OH)2]·H2O, the asymmetric unit comprises one stannate(IV) dianion, two organic cations and one water mol-ecule of crystallization. The [Sn(C2O4)2(OH)2](2-) dianion consists of an Sn(IV) atom chelated by two oxalate anions and coordinated by two OH(-) ligands in a cis octa-hedral arrangement. Neighbouring anions are connected through O-H?O hydrogen bonds between hydroxide groups and non-coordinating oxalate O atoms into layers expanding parallel to (100). In addition, cations and anions are linked through N-H?O hydrogen bonds, and the water mol-ecule bridges two anions with two O-H?O hydrogen bonds and is also the acceptor of an N-H?O hydrogen bond with one of the cations. Weak C-H?O hydrogen bonds are also observed. The intricate hydrogen bonding leads to the formation of a three-dimensional network.

SUBMITTER: Diop MB 

PROVIDER: S-EPMC4778813 | biostudies-other | 2016 Mar

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Crystal structure of bis-(2-methyl-1H-imidazol-3-ium) di-hydroxidobis(oxalato-κ(2) O (1),O (2))stannate(IV) monohydrate.

Diop Mouhamadou Birame MB   Diop Libasse L   Plasseraud Laurent L   Maris Thierry T  

Acta crystallographica. Section E, Crystallographic communications 20160217 Pt 3

In the structure of the hydrated title salt, (C4H7N2)2[Sn(C2O4)2(OH)2]·H2O, the asymmetric unit comprises one stannate(IV) dianion, two organic cations and one water mol-ecule of crystallization. The [Sn(C2O4)2(OH)2](2-) dianion consists of an Sn(IV) atom chelated by two oxalate anions and coordinated by two OH(-) ligands in a cis octa-hedral arrangement. Neighbouring anions are connected through O-H⋯O hydrogen bonds between hydroxide groups and non-coordinating oxalate O atoms into layers expan  ...[more]

Similar Datasets

Unknown Crystal structure of bis-(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis-[n-butyl-tri-chlorido-stannate(IV)].
| S-EPMC4908556 | biostudies-literature
Unknown Crystal structure of 2-methyl-1H-imidazol-3-ium aqua-tri-chlorido-(oxalato-?(2) O,O')stannate(IV).
| S-EPMC4420124 | biostudies-literature
Unknown Bis(cyclo-hexyl-ammonium) tetra-chlorido-(oxalato)stannate(IV).
| S-EPMC3793702 | biostudies-literature
Unknown Crystal structure of zwitterionic 3,3'-[1,1'-(butane-1,4-di-yl)bis-(1H-imidazol-3-ium-3,1-di-yl)]bis-(propane-1-sulfonate) dihydrate.
| S-EPMC7405557 | biostudies-literature
Unknown Crystal structure of di-chlorido-bis-(1,3,4,5-tetra-methyl-1H-imidazol-2-ium-2-thiol-ate-κS)nickel(II).
| S-EPMC4571377 | biostudies-literature
Unknown Bis(dicyclo-hexyl-ammonium) ?-oxalato-?O,O:O,O-bis-[aqua-(oxalato-?O,O)diphenyl-stannate(IV)].
| S-EPMC3011489 | biostudies-literature
Unknown 1,1'-[(Biphenyl-4,4'-di-yl)bis-(methyl-ene)]di-1H-imidazol-3-ium tetra-chlorido-mercurate(II).
| S-EPMC3238662 | biostudies-literature
Unknown Crystal structure of bis-[4-(di-methyl-amino)-pyridinium] aqua-bis-(oxalato)oxidovanadate(IV) dihydrate.
| S-EPMC4992925 | biostudies-literature
Unknown Bis(1H-imidazol-3-ium) naphthalene-1,5-disulfonate.
| S-EPMC3344631 | biostudies-literature
Unknown Crystal structure of bis-(diiso-propyl-ammonium) cis-di-iodido-bis-(oxolato-κ2O1,O2)stannate(IV).
| S-EPMC5946977 | biostudies-literature