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Crystal structure of di-chlorido-bis-(1,3,4,5-tetra-methyl-1H-imidazol-2-ium-2-thiol-ate-?S)nickel(II).

ABSTRACT: In the mol-ecular structure of the title compound, [NiCl2(C7H12N2S)2], the Ni(II) atom has a distorted tetra-hedral geometry, coordinated by two Cl atoms [Ni-Cl= 2.2336?(6)?Å] and two thione S atoms [Ni-S= 2.3024?(6)?Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axis, are Cl-Ni-Cl = 115.58?(3)° and S-Ni-S = 94.55?(3)°. All other angles at the central Ni(II) atom range from 109.46?(2) to 112.96?(2)°. The C-S-Ni angle is 99.91?(6)°. The planes of two imidazolium rings make a dihedral angle of 70.56?(6)°.

SUBMITTER: Ahmida A

PROVIDER: S-EPMC4571377 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of di-chlorido-bis-(1,3,4,5-tetra-methyl-1H-imidazol-2-ium-2-thiol-ate-κS)nickel(II).

Ahmida Aziza A Flörke Ulrich U Egold Hans H Henkel Gerald G

Acta crystallographica. Section E, Crystallographic communications 20150704 Pt 8

In the mol-ecular structure of the title compound, [NiCl2(C7H12N2S)2], the Ni(II) atom has a distorted tetra-hedral geometry, coordinated by two Cl atoms [Ni-Cl= 2.2336 (6) Å] and two thione S atoms [Ni-S= 2.3024 (6) Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axis, are Cl-Ni-Cl = 115.58 (3)° and S-Ni-S = 94.55 (3)°. All other angles at the central Ni(II) atom range from 109.46 (2) to 112.96 (2)°. The C-S-Ni angle is 99.91 (6)°. The planes of two imidazolium rings make ...[more]

PMID: 26396777

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