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[?2-trans-1,2-Bis-(pyridin-4-yl)ethene-?(2) N:N']bis-{[1,2-bis-(pyridin-4-yl)ethene-?N]bis-[N-(2-hydroxy-eth-yl)-N-iso-propyl-dithio-carbamato-?(2) S,S']cadmium} aceto-nitrile tetra-solvate: crystal structure and Hirshfeld surface analysis.

ABSTRACT: The asymmetric unit of the title compound, [Cd2(C12H10N2)3(C6H12NOS2)4]·4C2H3N, comprises a Cd(II) atom, two di-thio-carbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-yl-ethyl-ene (bpe) mol-ecules and two aceto-nitrile solvent mol-ecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe mol-ecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N2S4 coordination geometry is based on an octa-hedron. Supra-molecular layers, sustained by hy-droxy-O-H?O(hy-droxy) and hy-droxy-O-H?N(bpe) hydrogen bonding, inter-penetrate to form a three-dimensional architecture; voids in this arrangement are occupied by the aceto-nitrile solvent mol-ecules. Additional inter-molecular inter-actions falling within the specified framework have been analysed by Hirshfeld surface analysis, including ?-? inter-actions.

SUBMITTER: Jotani MM 

PROVIDER: S-EPMC4971847 | biostudies-other | 2016 Aug

REPOSITORIES: biostudies-other

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[μ2-trans-1,2-Bis-(pyridin-4-yl)ethene-κ(2) N:N']bis-{[1,2-bis-(pyridin-4-yl)ethene-κN]bis-[N-(2-hydroxy-eth-yl)-N-iso-propyl-dithio-carbamato-κ(2) S,S']cadmium} aceto-nitrile tetra-solvate: crystal structure and Hirshfeld surface analysis.

Jotani Mukesh M MM   Poplaukhin Pavel P   Arman Hadi D HD   Tiekink Edward R T ER  

Acta crystallographica. Section E, Crystallographic communications 20160712 Pt 8

The asymmetric unit of the title compound, [Cd2(C12H10N2)3(C6H12NOS2)4]·4C2H3N, comprises a Cd(II) atom, two di-thio-carbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-yl-ethyl-ene (bpe) mol-ecules and two aceto-nitrile solvent mol-ecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe mol-ecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N2S4 coordination geometr  ...[more]

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