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1-(Triethoxysilyl)buta-1,3-dienes-New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes.

ABSTRACT: A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1E,3E)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported.

SUBMITTER: Szudkowska-Fratczak J 

PROVIDER: S-EPMC5458880 | biostudies-other | 2015 Oct

REPOSITORIES: biostudies-other

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1-(Triethoxysilyl)buta-1,3-dienes-New Building Blocks for Stereoselective Synthesis of Unsymmetrical (<i>E</i>,<i>E</i>)-1,4-Disubstituted 1,3-dienes.

Szudkowska-Frątczak Justyna J   Taczała Mariusz M   Pawluć Piotr P  

Materials (Basel, Switzerland) 20151028 11

A convenient methodology for the highly stereoselective synthesis of unsymmetrical (1<i>E</i>,3<i>E</i>)-1,4-disubstituted 1,3-dienes based on palladium-catalyzed Hiyama cross-coupling reaction of 1-(triethoxysilyl)-substituted buta-1,3-dienes with aryl iodides is reported. ...[more]

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