Ontology highlight
ABSTRACT:
SUBMITTER: Comanescu CC
PROVIDER: S-EPMC5500858 | biostudies-other | 2015 Aug
REPOSITORIES: biostudies-other
Chemical science 20150518 8
A series of palladium(ii) radical carbene complexes, [PC˙(sp<sup>2</sup>)P]PdI, [PC˙(sp<sup>2</sup>)P]PdBr, and [PC˙(sp<sup>2</sup>)P]PdCl (PC(sp<sup>3</sup>)H<sub>2</sub>P = bis[2-(di-iso-propylphosphino)-phenyl]methane), is described. Compound [PC˙(sp<sup>2</sup>)P]PdI dimerizes to {[PC(sp<sup>2</sup>)P]PdI}<sub>2</sub> in the solid state, akin to the formation of Gomberg's dimer. While the bromo and the iodo derivatives could be obtained from the oxidation of [PC(sp<sup>2</sup>)P]Pd(PMe<sub>3 ...[more]