Ontology highlight
ABSTRACT:
SUBMITTER: Li Q
PROVIDER: S-EPMC3201350 | biostudies-literature | 2011 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20110920 Pt 10
The title complex, [(C(4)H(9))(4)N](2)[Mo(6)(C(7)H(6)ClN)O(18)], was prepared by the reaction of (Bu(4)N)(4)[α-Mo(8)O(26)] and 2-methyl-5-chloro-aniline hydro-chloride with N,N'-dicyclo-hexyl-carbodiimide as dehydrating agent in dry acetonitrile solution. The aryl-imido ligand is linked to an Mo atom of the Lindqvist-type hexamolybdate anion by an Mo N triple bond, with a bond length of 1.732 (4) Å and an Mo N-C bond angle of 169.1 (4)°, typical for monodentate imido groups in such hybrid comple ...[more]