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Tetra-ammonium diaqua-diperoxidoocta-molybdate(VI) tetra-hydrate.

ABSTRACT: The title compound (NH(4))(4)[Mo(8)O(24)(O(2))(2)(H(2)O)(2)]·4H(2)O, consists of an octa-molybdate cluster with a crystallographic centre of symmetry. The clusters pack in a cubic close packing arrangement defining channels containing water mol-ecules and ammonium cations, which exhibit hydrogen bonding with neighbouring clusters. Hydrogen bonding also exists between the coordinated water mol-ecules of one cluster with one of the O atoms of the peroxido fragment in a neighbouring cluster.

SUBMITTER: Ward AJ

PROVIDER: S-EPMC2969302 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Tetra-ammonium diaqua-diperoxidoocta-molybdate(VI) tetra-hydrate.

Ward Antony J AJ Arrow Gregory J GJ Maschmeyer Thomas T Masters Anthony F AF Turner Peter P Clegg Jack K JK

Acta crystallographica. Section E, Structure reports online 20090627 Pt 7

The title compound (NH(4))(4)[Mo(8)O(24)(O(2))(2)(H(2)O)(2)]·4H(2)O, consists of an octa-molybdate cluster with a crystallographic centre of symmetry. The clusters pack in a cubic close packing arrangement defining channels containing water mol-ecules and ammonium cations, which exhibit hydrogen bonding with neighbouring clusters. Hydrogen bonding also exists between the coordinated water mol-ecules of one cluster with one of the O atoms of the peroxido fragment in a neighbouring cluster. ...[more]

PMID: 21582647

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