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Dibromidotetra-kis(1H-indazole-κN)copper(II).


ABSTRACT: The Cu atom in the title compound, [CuBr(2)(C(7)H(6)N(2))(4)], is surrounded by four N-heterocycles that define an N(4) square-planar geometry. The coordination geometry is distorted towards an elongated octa-hedron owing to the presence of the two Br(-) anions, which are located at about 3 Å above and below the square plane. There are two independent molecules in the asymmetric unit, each with their Cu atom lying on an inversion centre.

SUBMITTER: Hossaini Sadr M 

PROVIDER: S-EPMC2915062 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Dibromidotetra-kis(1H-indazole-κN)copper(II).

Hossaini Sadr Moayad M   Soltani Behzad B   Gao Shan S   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1


The Cu atom in the title compound, [CuBr(2)(C(7)H(6)N(2))(4)], is surrounded by four N-heterocycles that define an N(4) square-planar geometry. The coordination geometry is distorted towards an elongated octa-hedron owing to the presence of the two Br(-) anions, which are located at about 3 Å above and below the square plane. There are two independent molecules in the asymmetric unit, each with their Cu atom lying on an inversion centre. ...[more]

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