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Bromidotetra-kis-(2-ethyl-1H-imidazole-?N (3))copper(II) bromide.

ABSTRACT: The Cu(II) ion in the title mol-ecular salt, [CuBr(C5H8N2)4]Br, is coordinated in a square-pyramidal geometry by four N atoms of imidazole ligands and one bromide anion in the apical position. In the crystal, the ions are linked by N-H?Br hydrogen bonds involving both the coordinating and the free bromide species as acceptors. A C-H?Br inter-action is also observed. Overall, a three-dimensional network results.

SUBMITTER: Godlewska S

PROVIDER: S-EPMC3588773 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Bromidotetra-kis-(2-ethyl-1H-imidazole-κN (3))copper(II) bromide.

Godlewska Sylwia S Kelm Harald H Krüger Hans-Jörg HJ Dołęga Anna A

Acta crystallographica. Section E, Structure reports online 20121124 Pt 12

The Cu(II) ion in the title mol-ecular salt, [CuBr(C5H8N2)4]Br, is coordinated in a square-pyramidal geometry by four N atoms of imidazole ligands and one bromide anion in the apical position. In the crystal, the ions are linked by N-H⋯Br hydrogen bonds involving both the coordinating and the free bromide species as acceptors. A C-H⋯Br inter-action is also observed. Overall, a three-dimensional network results. ...[more]

PMID: 23468738

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